Free radical mediated bromization of methylenecyclopropanes:Preparation of 2,4-dibromobutenes without transition metal

Lei Yu Bo Chen Xian Huang Lu Ling Wu

引用本文: Lei Yu,  Bo Chen,  Xian Huang,  Lu Ling Wu. Free radical mediated bromization of methylenecyclopropanes:Preparation of 2,4-dibromobutenes without transition metal[J]. Chinese Chemical Letters, 2007, 18(2): 121-123. doi: 10.1016/j.cclet.2006.12.004 shu
Citation:  Lei Yu,  Bo Chen,  Xian Huang,  Lu Ling Wu. Free radical mediated bromization of methylenecyclopropanes:Preparation of 2,4-dibromobutenes without transition metal[J]. Chinese Chemical Letters, 2007, 18(2): 121-123. doi: 10.1016/j.cclet.2006.12.004 shu

Free radical mediated bromization of methylenecyclopropanes:Preparation of 2,4-dibromobutenes without transition metal

摘要: A series of 2,4-dibromobutenes were synthesized by the reaction of methylenecyclopropanes with KBr in HOAc in the presence of dibenzoyl peroxide, providing an environment friendly method for the synthesis of 2,4-dibromobutenes.

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  • 收稿日期:  2006-07-10
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    沈阳化工大学材料科学与工程学院 沈阳 110142

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