An Improved Synthesis of dl-Muscone

Han Song CHEN Xiu Fang LIU Han Sheng XU

引用本文: Han Song CHEN,  Xiu Fang LIU,  Han Sheng XU. An Improved Synthesis of dl-Muscone[J]. Chinese Chemical Letters, 1997, 8(1): 17-18. shu
Citation:  Han Song CHEN,  Xiu Fang LIU,  Han Sheng XU. An Improved Synthesis of dl-Muscone[J]. Chinese Chemical Letters, 1997, 8(1): 17-18. shu

An Improved Synthesis of dl-Muscone

摘要: M.Stoll's total synthetic route for dl-muscone was improved. 2.15-Hexadecanedione was synthesized by PTC method.and converted into dehydromuscones through intramolecular aldol reaction by the mixture of zinc chloride and the Grinard reagent of isoamyl bromide used as condensing agent.Catalytic hydrogenation of dehydromuscones gave dl-muscone.

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  • 收稿日期:  1996-09-07
通讯作者: 陈斌, bchen63@163.com
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    沈阳化工大学材料科学与工程学院 沈阳 110142

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