引用本文:
Jin Pei CHENG, Zi Rong ZHENG. Trapping of the Dichlorocarbene Intermediate in the Reactionof α-Cyanobenzyl carbanion with Carbon Tetrachloride[J]. Chinese Chemical Letters,
1998, 9(10): 895-896.
Citation: Jin Pei CHENG, Zi Rong ZHENG. Trapping of the Dichlorocarbene Intermediate in the Reactionof α-Cyanobenzyl carbanion with Carbon Tetrachloride[J]. Chinese Chemical Letters, 1998, 9(10): 895-896.
Citation: Jin Pei CHENG, Zi Rong ZHENG. Trapping of the Dichlorocarbene Intermediate in the Reactionof α-Cyanobenzyl carbanion with Carbon Tetrachloride[J]. Chinese Chemical Letters, 1998, 9(10): 895-896.
Trapping of the Dichlorocarbene Intermediate in the Reactionof α-Cyanobenzyl carbanion with Carbon Tetrachloride
摘要:
In Me2SO, an X-philic reaction took place between α-cyanobenzyl carbanion and CCl4. The intermediate dichlorocarbene was trapped by the primary product dicyanostilbene to give the alkene-carbene adduct, 1,l-dichloro-2,3-dicyano-2,3-diphenylcyclopropane.
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关键词:
- dichlorocarbene
- / SN2 vs. ET mechanism
- / CCl4
English
Trapping of the Dichlorocarbene Intermediate in the Reactionof α-Cyanobenzyl carbanion with Carbon Tetrachloride
Abstract:
In Me2SO, an X-philic reaction took place between α-cyanobenzyl carbanion and CCl4. The intermediate dichlorocarbene was trapped by the primary product dicyanostilbene to give the alkene-carbene adduct, 1,l-dichloro-2,3-dicyano-2,3-diphenylcyclopropane.
-
Key words:
- dichlorocarbene
- / SN2 vs. ET mechanism
- / CCl4
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