引用本文:
Yi Min SHE, Ya Ping TU, Xing Hua GUO, Zi Yang LIU, Shu Ying LIU. REACTIONS OF C60 WITH R3SnH:A NEW SYNTHETIC TO C60(RH)n AND THE PROPERTY OF C60 TO CATALYZE RADICAL REACTIONS[J]. Chinese Chemical Letters,
1996, 7(5): 433-436.
Citation: Yi Min SHE, Ya Ping TU, Xing Hua GUO, Zi Yang LIU, Shu Ying LIU. REACTIONS OF C60 WITH R3SnH:A NEW SYNTHETIC TO C60(RH)n AND THE PROPERTY OF C60 TO CATALYZE RADICAL REACTIONS[J]. Chinese Chemical Letters, 1996, 7(5): 433-436.
Citation: Yi Min SHE, Ya Ping TU, Xing Hua GUO, Zi Yang LIU, Shu Ying LIU. REACTIONS OF C60 WITH R3SnH:A NEW SYNTHETIC TO C60(RH)n AND THE PROPERTY OF C60 TO CATALYZE RADICAL REACTIONS[J]. Chinese Chemical Letters, 1996, 7(5): 433-436.
REACTIONS OF C60 WITH R3SnH:A NEW SYNTHETIC TO C60(RH)n AND THE PROPERTY OF C60 TO CATALYZE RADICAL REACTIONS
摘要:
A new method for the preparation of polyalkyl and polyarenefullerene derivatives C60(RH)n (R=Bu,n=1-3;R=Ph,n=1-10) by the reaction of C60 with organotin hydride in toluene is described.Another series of products of stannanes RaSnbHc (R=Bu,a=3-8,b=1-4,c=0-3;R=Ph,a=3-11,b=1-5,c=0-4) were also obtained,which shows that C60 can catalyze polymerization of organic-tin.These products were determined by mass and infrared spectrometry.And the possible reaction mechanisms are discussed.
English
REACTIONS OF C60 WITH R3SnH:A NEW SYNTHETIC TO C60(RH)n AND THE PROPERTY OF C60 TO CATALYZE RADICAL REACTIONS
Abstract:
A new method for the preparation of polyalkyl and polyarenefullerene derivatives C60(RH)n (R=Bu,n=1-3;R=Ph,n=1-10) by the reaction of C60 with organotin hydride in toluene is described.Another series of products of stannanes RaSnbHc (R=Bu,a=3-8,b=1-4,c=0-3;R=Ph,a=3-11,b=1-5,c=0-4) were also obtained,which shows that C60 can catalyze polymerization of organic-tin.These products were determined by mass and infrared spectrometry.And the possible reaction mechanisms are discussed.
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