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Ming Bao HUANG. THE 4Σ- STATES OF THE FO RADICAL[J]. Chinese Chemical Letters,
1996, 7(5): 475-478.
Citation: Ming Bao HUANG. THE 4Σ- STATES OF THE FO RADICAL[J]. Chinese Chemical Letters, 1996, 7(5): 475-478.
Citation: Ming Bao HUANG. THE 4Σ- STATES OF THE FO RADICAL[J]. Chinese Chemical Letters, 1996, 7(5): 475-478.
THE 4Σ- STATES OF THE FO RADICAL
摘要:
For investigating the 4Σ-→ 4Σ- transition in the FO radical to which an observed 268 nm ASE line has been attributed,the potential energy curves of the four lowest-lying 4A2 states of FO have been calculated using the MRSDCI method.The results indicate that the first 4Σ- (l4A2) and the upper 4Σ-(44A2) states are weakly bound and bound states respectively,and the 24A2 and 34A2 states are both repulsive states which are not relevant to the emission.The predicted Te value for the 4Σ-→ 4Σ- transition is 4.62 eV,which is in excellent agreement with the photon energy value (4.63 eV) of the ASE line.The procedure of our MRSDCI calculations for excited states is described in detail,and the previous calculation results for these states are discussed.
English
THE 4Σ- STATES OF THE FO RADICAL
Abstract:
For investigating the 4Σ-→ 4Σ- transition in the FO radical to which an observed 268 nm ASE line has been attributed,the potential energy curves of the four lowest-lying 4A2 states of FO have been calculated using the MRSDCI method.The results indicate that the first 4Σ- (l4A2) and the upper 4Σ-(44A2) states are weakly bound and bound states respectively,and the 24A2 and 34A2 states are both repulsive states which are not relevant to the emission.The predicted Te value for the 4Σ-→ 4Σ- transition is 4.62 eV,which is in excellent agreement with the photon energy value (4.63 eV) of the ASE line.The procedure of our MRSDCI calculations for excited states is described in detail,and the previous calculation results for these states are discussed.
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