引用本文:
Song Lin ZHANG, Yong Min ZHANG. Samarium Diiodide-Induced Reductive Cleavage of Se-St Bond in Arylselenotrimethylsilane Leading to the Formation of Samarium Arylselenolate:Synthesis of β-Arylseleno Estsrs and β-Arylseleno Nitriles[J]. Chinese Chemical Letters,
1998, 9(10): 885-887.
Citation: Song Lin ZHANG, Yong Min ZHANG. Samarium Diiodide-Induced Reductive Cleavage of Se-St Bond in Arylselenotrimethylsilane Leading to the Formation of Samarium Arylselenolate:Synthesis of β-Arylseleno Estsrs and β-Arylseleno Nitriles[J]. Chinese Chemical Letters, 1998, 9(10): 885-887.
Citation: Song Lin ZHANG, Yong Min ZHANG. Samarium Diiodide-Induced Reductive Cleavage of Se-St Bond in Arylselenotrimethylsilane Leading to the Formation of Samarium Arylselenolate:Synthesis of β-Arylseleno Estsrs and β-Arylseleno Nitriles[J]. Chinese Chemical Letters, 1998, 9(10): 885-887.
Samarium Diiodide-Induced Reductive Cleavage of Se-St Bond in Arylselenotrimethylsilane Leading to the Formation of Samarium Arylselenolate:Synthesis of β-Arylseleno Estsrs and β-Arylseleno Nitriles
摘要:
The Se-Si bond in arylselenotrimethylsilane was reduced by samarium diiodide to produce samarium arylselenolate, which reacted with α,β-unsaturated esters or α,β-unsaturated nitriles to give β-selenoesters and β-selenonitriles, respectively.
English
Samarium Diiodide-Induced Reductive Cleavage of Se-St Bond in Arylselenotrimethylsilane Leading to the Formation of Samarium Arylselenolate:Synthesis of β-Arylseleno Estsrs and β-Arylseleno Nitriles
Abstract:
The Se-Si bond in arylselenotrimethylsilane was reduced by samarium diiodide to produce samarium arylselenolate, which reacted with α,β-unsaturated esters or α,β-unsaturated nitriles to give β-selenoesters and β-selenonitriles, respectively.
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Key words:
- samarium diiodide
- / arylselenotrimethylsilane
- / arylseleno esters
- / arylseleno nitriles
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