引用本文:
Cheng Hui Sun, Xin Qi Zhao, Yu Chuan Li, Si Ping Pang. Synthesis of two new cage molecules containing trinitromethyl group[J]. Chinese Chemical Letters,
2010, 21(5): 572-575.
doi:
10.1016/j.cclet.2009.12.001
Citation: Cheng Hui Sun, Xin Qi Zhao, Yu Chuan Li, Si Ping Pang. Synthesis of two new cage molecules containing trinitromethyl group[J]. Chinese Chemical Letters, 2010, 21(5): 572-575. doi: 10.1016/j.cclet.2009.12.001
Citation: Cheng Hui Sun, Xin Qi Zhao, Yu Chuan Li, Si Ping Pang. Synthesis of two new cage molecules containing trinitromethyl group[J]. Chinese Chemical Letters, 2010, 21(5): 572-575. doi: 10.1016/j.cclet.2009.12.001
Synthesis of two new cage molecules containing trinitromethyl group
摘要:
Two new cage compounds,4-trinitroethyl-10-nitro-2,6,8,12-tetraacetylhexaazaisowurtzitane (3) and 4-trinitroethyl-2,6,8,10,12-pentanitrohexaazaisowurtzitane (4), containing trinitromethyl group were synthesized by a novel method, and their structures were confirmed by IR, 1H NMR, MS and single crystal X-ray. DSC result shows that compound 4 has surprising thermal stability and could be a potential energetic compound.
English
Synthesis of two new cage molecules containing trinitromethyl group
Abstract:
Two new cage compounds,4-trinitroethyl-10-nitro-2,6,8,12-tetraacetylhexaazaisowurtzitane (3) and 4-trinitroethyl-2,6,8,10,12-pentanitrohexaazaisowurtzitane (4), containing trinitromethyl group were synthesized by a novel method, and their structures were confirmed by IR, 1H NMR, MS and single crystal X-ray. DSC result shows that compound 4 has surprising thermal stability and could be a potential energetic compound.
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Key words:
- Cage compound
- / Trinitromethyl group
- / Synthesis
- / X-ray crystal structure
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