引用本文:
Xiu Min SHEN, Liang Dong SUN, Cong ZHANG. Studies on Diastereoselective Intramolecular meta-Cycloaddition of Arene to Olefin (Part Ⅱ)[J]. Chinese Chemical Letters,
1998, 9(4): 321-323.
Citation: Xiu Min SHEN, Liang Dong SUN, Cong ZHANG. Studies on Diastereoselective Intramolecular meta-Cycloaddition of Arene to Olefin (Part Ⅱ)[J]. Chinese Chemical Letters, 1998, 9(4): 321-323.
Citation: Xiu Min SHEN, Liang Dong SUN, Cong ZHANG. Studies on Diastereoselective Intramolecular meta-Cycloaddition of Arene to Olefin (Part Ⅱ)[J]. Chinese Chemical Letters, 1998, 9(4): 321-323.
Studies on Diastereoselective Intramolecular meta-Cycloaddition of Arene to Olefin (Part Ⅱ)
摘要:
The photoinduced intramolecular meta-cycloaddition of bichromophores 1a-1d gave diastereoselectively two types of adducts 2a-2d and 3a-3d respectively. The observed stereochemistry of cycloaddition is rationalized in terms of hydrogen bond effect induced by the 4-hydroxy group in the 5-phenylpent-1-ene skeleton.
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关键词:
- Arene
- / Olefin
- / meta-Cycloaddition
- / Diastereoselectivity
English
Studies on Diastereoselective Intramolecular meta-Cycloaddition of Arene to Olefin (Part Ⅱ)
Abstract:
The photoinduced intramolecular meta-cycloaddition of bichromophores 1a-1d gave diastereoselectively two types of adducts 2a-2d and 3a-3d respectively. The observed stereochemistry of cycloaddition is rationalized in terms of hydrogen bond effect induced by the 4-hydroxy group in the 5-phenylpent-1-ene skeleton.
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Key words:
- Arene
- / Olefin
- / meta-Cycloaddition
- / Diastereoselectivity
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