正一元醇链长对吗啉的偶极相互作用的影响

引用本文: PRIYA B, PALANIAPPAN L. 正一元醇链长对吗啉的偶极相互作用的影响[J]. 物理化学学报, 2016, 32(4): 855-862. doi: 10.3866/PKU.WHXB201601081 shu

Citation: PRIYA B, PALANIAPPAN L. Effect of Chain Length on the Dipolar Interaction of Morpholine with Primary Alkanols[J]. Acta Physico-Chimica Sinica, 2016, 32(4): 855-862. doi: 10.3866/PKU.WHXB201601081 shu

正一元醇链长对吗啉的偶极相互作用的影响

PRIYA B ^1, ,
PALANIAPPAN L ^2,

1.
1. Department of Physics, Manonmaniyam Sundaranar University, Tirunelveli, TN 627012, India;
2.
2. Physics Wing, D.D.E, Annamalai University, TN 608002, India

摘要: Sound velocity, density, and viscosity values have been measured at T = 303 K for four binary systems of morpholine + methanol, ethanol, 1-propanol, and 1-butanol. From these data, acoustical parameters, such as adiabatic compressibility, free length, free volume, and internal pressure, have been estimated using the standard relations. The results are interpreted in terms of the molecular interaction between the components of the mixtures. The observed excess values in all the mixtures indicate that the molecular symmetry existing in the system is highly disturbed by the addition of morpholine molecules. The interaction energy terms of the statistical mixing are also verified for these binary systems, and the dipole-dipole interactions are found to be predominant and are greatly affected by the chain length of the primary alkanols.

关键词:

English

Effect of Chain Length on the Dipolar Interaction of Morpholine with Primary Alkanols

PRIYA B ^1, ,
PALANIAPPAN L ^2,

1.
1. Department of Physics, Manonmaniyam Sundaranar University, Tirunelveli, TN 627012, India;
2.
2. Physics Wing, D.D.E, Annamalai University, TN 608002, India
Received Date: 07 August 2015
Available Online: 08 January 2016

Abstract: Sound velocity, density, and viscosity values have been measured at T = 303 K for four binary systems of morpholine + methanol, ethanol, 1-propanol, and 1-butanol. From these data, acoustical parameters, such as adiabatic compressibility, free length, free volume, and internal pressure, have been estimated using the standard relations. The results are interpreted in terms of the molecular interaction between the components of the mixtures. The observed excess values in all the mixtures indicate that the molecular symmetry existing in the system is highly disturbed by the addition of morpholine molecules. The interaction energy terms of the statistical mixing are also verified for these binary systems, and the dipole-dipole interactions are found to be predominant and are greatly affected by the chain length of the primary alkanols.

Key words:

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正一元醇链长对吗啉的偶极相互作用的影响

English

Effect of Chain Length on the Dipolar Interaction of Morpholine with Primary Alkanols

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正一元醇链长对吗啉的偶极相互作用的影响

English

Effect of Chain Length on the Dipolar Interaction of Morpholine with Primary Alkanols

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

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CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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