快速合成廉价CuMo纳米粒子高效催化氨硼烷水解产氢

引用本文: 杨昆, 姚淇露, 卢章辉, 康志兵, 陈祥树. 快速合成廉价CuMo纳米粒子高效催化氨硼烷水解产氢[J]. 物理化学学报, 2017, 33(5): 993-1000. doi: 10.3866/PKU.WHXB201702087 shu

Citation: YANG Kun, YAO Qi-Lu, LU Zhang-Hui, KANG Zhi-Bing, CHEN Xiang-Shu. Facile Synthesis of CuMo Nanoparticles as Highly Active and Cost-Effective Catalysts for the Hydrolysis of Ammonia Borane[J]. Acta Physico-Chimica Sinica, 2017, 33(5): 993-1000. doi: 10.3866/PKU.WHXB201702087 shu

快速合成廉价CuMo纳米粒子高效催化氨硼烷水解产氢

1.
江西师范大学化学化工学院, 无机膜材料工程技术研究中心, 南昌 330022;
2.
南昌航空大学航天制造工程学院, 南昌 330036
基金项目:
国家自然科学基金（21463012），江西省青年科学家培养对象（20133BCB23011）及江西省赣鄱英才555 工程资助

摘要: 在无表面活性剂和载体的情况下，使用硼氢化钠作为还原剂，简单快速地合成了CuMo非贵金属纳米粒子。采用X射线粉末衍射（XRD）、透射电子显微镜（TEM）、高分辨透射电子显微镜（HRTEM）、选区电子衍射（SAED）、电感耦合等离子体原子发射光谱（ICP-AES）、光电子能谱（XPS）和比表面积分析（BET）等方法详细地表征了所合成的CuMo纳米粒子，并在室温下将其用于催化氨硼烷水解产氢。所合成的Cu_0.9Mo_0.1纳米粒子对于氨硼烷水解制氢表现出优异的催化性能，在室温下其转化频率（TOF）达到14.9 min^-1，在已报道的Cu催化剂中处于相对较高的值。这种简单的合成方法不仅仅局限于合成CuMo纳米粒子，还可以扩展到合成CuW（3.6 min^-1）、CuCr（2 min^-1）、NiMo（55.6 min^-1）和CoMo（21.7 min^-1）纳米粒子，它提供了一种普适的方法合成Cu-M（M = Mo，W，Cr）和TM-Mo（TM = Cu，Ni，Co）纳米粒子作为一系列新型催化剂用于氨硼烷水解。双金属纳米粒子增强的催化活性归因于应力和配体效应诱导的Cu-M纳米粒子的协同促进效果。

关键词:

铜
/ 氨硼烷
/ 水解
/ 氢能源
/ 纳米粒子

English

Facile Synthesis of CuMo Nanoparticles as Highly Active and Cost-Effective Catalysts for the Hydrolysis of Ammonia Borane

1.
Jiangxi Inorganic Membrane Materials Engineering Research Centre, College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, P. R. China;
2.
School of Aeronautical Manufacture Engineering, Nanchang Hangkong University, Nanchang 330036, P. R. China
Received Date: 15 December 2016
Revised Date: 21 January 2017
Available Online: 08 February 2017
Fund Project:
The project was supported by the National Natural Science Foundation of China (21463012), Young Scientist Foundation of Jiangxi Province, China (20133BCB23011), and“Gan-po talent 555”Project of Jiangxi Province, China.

Abstract: Noble-metal-free CuMo nanoparticles (NPs) without surfactant or support have been facilely prepared using NaBH₄ as a reducing agent. The as-prepared CuMo nanocatalysts were characterized using X-ray diffraction (XRD), transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM), selected area electron diffraction (SAED), inductively coupled plasma-atomic emission spectroscopy (ICP-AES), X-ray photoelectron spectroscopy (XPS), and Brunauer-Emmett-Teller (BET) surface area measurements, and used as catalysts for the hydrolysis of ammonia borane (AB, NH₃BH₃) at room temperature. The as-synthesized Cu_0.9Mo_0.1 NPs exhibited a high activity towards the hydrolysis of AB with a turnover frequency (TOF) of 14.9 min^-1, a higher value than that reported for Cu catalysts. Our synthesis is not limited to CuMo NPs alone, but can easily be extended to CuW (3.6 min^-1), CuCr (2 min^-1), NiMo (55.6 min^-1), and CoMo (21.7 min^-1) NPs, providing a general approach to Cu-M (M = Mo, W, Cr) and TM-Mo (TM = Cu, Ni, Co) NPs as a series of novel catalysts for the hydrolysis of AB. The enhanced activity of bimetallic NPs may be attributed to the synergistic effects of the Cu-M NPs induced by the strain and ligand effects.

Key words:

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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

快速合成廉价CuMo纳米粒子高效催化氨硼烷水解产氢

English

Facile Synthesis of CuMo Nanoparticles as Highly Active and Cost-Effective Catalysts for the Hydrolysis of Ammonia Borane

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

快速合成廉价CuMo纳米粒子高效催化氨硼烷水解产氢

English

Facile Synthesis of CuMo Nanoparticles as Highly Active and Cost-Effective Catalysts for the Hydrolysis of Ammonia Borane

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

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