硫粉为硫源，多元醇辅助合成硫化钼纳米片

引用本文: 王辉, 邹德春. 硫粉为硫源，多元醇辅助合成硫化钼纳米片[J]. 物理化学学报, 2017, 33(5): 1027-1032. doi: 10.3866/PKU.WHXB201702081 shu

Citation: WANG Hui, ZOU De-Chun. Polyol-Mediated Synthesis of MoS₂ Nanosheets Using Sulfur Powder as the Sulfur Source[J]. Acta Physico-Chimica Sinica, 2017, 33(5): 1027-1032. doi: 10.3866/PKU.WHXB201702081 shu

硫粉为硫源，多元醇辅助合成硫化钼纳米片

王辉 ^1, ,
邹德春 ^1,2,

1.
中国科学院北京纳米能源与系统研究所, 国家纳米科学中心, 北京 100083;
2.
北京大学化学与分子工程学院, 北京 100871
基金项目:
国家顶尖千人计划，国家自然科学基金（51573004，91333107）及北京市自然科学基金（Z160002）资助项目

摘要: 本文以普通硫粉和钼酸钠为原料，通过两相法在170－200 ℃下经8 h制备得到二硫化钼纳米片，同时基于聚集-聚并模型提出其三步法生长机理。其中，硫粉的再组装保证了其向H₂S的转化，使钼酸钠得以还原，因此在本方法中起到关键作用。本法制备得到的硫化钼纳米片富含可能由于各种位错引起的未饱和硫原子，有利于其在催化加氢等领域的应用。此外，由于二维过渡金属硫族化合物结构相似，所以本方法及其机理可能同样适用于其他二维过渡金属硫族化合物。本方法为绿色、便捷制备二硫化钼纳米片提供了一个选择。

关键词:

English

Polyol-Mediated Synthesis of MoS₂ Nanosheets Using Sulfur Powder as the Sulfur Source

WANG Hui ^1, ,
ZOU De-Chun ^1,2,

1.
Beijing Institute of Nanoenergy and Nanosystems, Chinese Academy of Sciences, National Center for Nanoscience and Technology, Beijing 100083, P. R. China;
2.
College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China
Received Date: 23 November 2016
Revised Date: 06 February 2017
Available Online: 08 February 2017
Fund Project:
The project was supported by the“Thousand Talents”Program of China for Pioneering Researchers and Innovative Teams, National Natural Science Foundation of China (51573004, 91333107), and Natural Science Foundation of Beijing, China (Z160002).

Abstract: MoS₂ nanosheets are prepared with sulfur powder and Na₂MoO₄ by a one-pot two-phase method at 170－200 ℃ for 8 h. In addition, a three-step growth mechanism based on the aggregation and coalescence model is proposed. The reassembly of sulfur powder ensures the transformation from sulfur powder to H₂S to reduce Na₂MoO₄ and plays a key role in the successful preparation of MoS₂ nanosheets. The as-prepared MoS₂ nanosheets are rich in unsaturated sulfur atoms, probably resulting from the dislocation cores of the MoS₂ nanosheets, which have been found to be beneficial for hydrogen evolution reaction catalysis. The method and growth mechanism adopted in this study may be applied to other transition metal dichalogenides for similar structures. The facile and green method provides an alternative for the preparation of MoS₂ nanosheets.

Key words:

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沈阳化工大学材料科学与工程学院沈阳 110142

硫粉为硫源，多元醇辅助合成硫化钼纳米片

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