Citation:
RANDOM COPOLYMER OF PROPYLENE OXIDE AND ETHYLENE OXIDE PREPARED BY DOUBLE METAL CYANIDE COMPLEX CATALYST[J]. Chinese Journal of Polymer Science,
2002, 20(5): 453-459.
RANDOM COPOLYMER OF PROPYLENE OXIDE AND ETHYLENE OXIDE PREPARED BY DOUBLE METAL CYANIDE COMPLEX CATALYST
摘要:
Copolymerization of propylene oxide (PO) and ethylene oxide (EO) using double metal cyanide (DMC) complexas the catalyst was carried out. The structure of random copolymers was confirmed by 13C-NMR and IR spectra. 1H-NMRanalysis shows that the EO content in the copolymer is the same as that in the initial monomer feed. Moderate molecularweight copolymers with various EO content were obtained and their values of molecular weigh distribution (MWD) fell inthe range of 1.21-1.55. It was found that the molecular weight of copolymers is controlled by the mass ratio of EO+PO to initiator moles used.The reaction rate as well as polymer yield decrease with increasing EO content in the feed composition.
English
RANDOM COPOLYMER OF PROPYLENE OXIDE AND ETHYLENE OXIDE PREPARED BY DOUBLE METAL CYANIDE COMPLEX CATALYST
Abstract:
Copolymerization of propylene oxide (PO) and ethylene oxide (EO) using double metal cyanide (DMC) complexas the catalyst was carried out. The structure of random copolymers was confirmed by 13C-NMR and IR spectra. 1H-NMRanalysis shows that the EO content in the copolymer is the same as that in the initial monomer feed. Moderate molecularweight copolymers with various EO content were obtained and their values of molecular weigh distribution (MWD) fell inthe range of 1.21-1.55. It was found that the molecular weight of copolymers is controlled by the mass ratio of EO+PO to initiator moles used.The reaction rate as well as polymer yield decrease with increasing EO content in the feed composition.
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