多元光学计算与下一代光谱仪

引用本文: 段潮舒, 蔡文生, 邵学广. 多元光学计算与下一代光谱仪[J]. 分析化学, 2021, 49(4): 593-601. doi: 10.19756/j.issn.0253-3820.201436 shu

Citation: DUAN Chao-Shu, CAI Wen-Sheng, SHAO Xue-Guang. Multivariate Optical Computing and Next-generation Spectrometer[J]. Chinese Journal of Analytical Chemistry, 2021, 49(4): 593-601. doi: 10.19756/j.issn.0253-3820.201436 shu

多元光学计算与下一代光谱仪

1.
南开大学化学学院分析科学研究中心, 天津 300071;
2.
天津市生物传感与分子识别重点实验室, 天津 300071;
3.
药物化学生物学国家重点实验室, 天津 300071

通讯作者: 邵学广,E-mail:xshao@nankai.edu.cn

基金项目:
国家自然科学基金项目（No.21775076）和南开大学中央高校基本科研基金项目（No.63191743）资助。

摘要: 多元光学计算（Multivariate optical computing，MOC）是一种在光学测量过程中利用光学滤波器实现光学计算的方法，基于MOC的分析仪器通过单点检测器即可获得定性和定量分析结果，不需要复杂的仪器设计和繁琐的数据处理过程。MOC的关键是滤波器，需根据分析目标设计合适的滤波器，检测信号可直接反映分析结果。近年来，科研人员不断对滤波器的设计进行优化和改进，光学运算性能不断提高。基于MOC的光谱仪是化学计量学和仪器设计的完美结合，被称为"下一代光谱仪"。本文阐述了MOC方法的发展历史、MOC光谱仪的原理和近年来的主要研究进展，总结了滤波器的设计方法、滤波器的光学器件和MOC光谱仪的应用，探讨了基于MOC的光谱仪在滤波器的设计及光学实现、系统集成等方面面临的挑战。

关键词:

English

Multivariate Optical Computing and Next-generation Spectrometer

1.
Research Center for Analytical Sciences, College of Chemistry, Nankai University, Tianjin 300071, China;
2.
Tianjin Key Laboratory of Biosensing and Molecular Recognition, Tianjin 300071, China;
3.
State Key Laboratory of Medicinal Chemical Biology, Tianjin 300071, China

Corresponding author: SHAO Xue-Guang, xshao@nankai.edu.cn

Received Date: 26 July 2020
Revised Date: 19 October 2020
Fund Project:
Supported by the National Natural Science Foundation of China (No.21775076) and the Foundation Research Funds for the Central Universities, Nankai University (No. 63191743).

Abstract: Multivariate optical computing (MOC) is a technique that uses optical filters to modulate the light to achieve calculation and obtain qualitative or quantitative results directly by a single-point detector. Therefore, the complicated instrument design and cumbersome data processing are no longer needed for the MOC-based analytical instrument. The key technique for MOC is the design of the filter to achieve the detection that directly reflects the result for different purposes. In recent years, much efforts have been made for designation and optimization of the filters to enhance the performance. MOC-based spectrometer is a perfect combination of chemometrics and instrument design, and thus it is praised as the next-generation spectrometer. In this paper, the history, principle and recent advances of MOC related techniques were summarized with an emphasis on the filter design, filter optics and applications, and the challenges in the design and the optical implementation of the filters were discussed, as well as the integration of the instrument system.

Key words:

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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

多元光学计算与下一代光谱仪

通讯作者: 邵学广,E-mail:xshao@nankai.edu.cn

English

Multivariate Optical Computing and Next-generation Spectrometer

Corresponding author: SHAO Xue-Guang, xshao@nankai.edu.cn

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

多元光学计算与下一代光谱仪

通讯作者: 邵学广,E-mail:xshao@nankai.edu.cn

English

Multivariate Optical Computing and Next-generation Spectrometer

Corresponding author: SHAO Xue-Guang, xshao@nankai.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

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CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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