引用本文:
Yan Bing ZU, Pei Fang LIU, Chuan Sin CHA, Xi LI. Investigation of the Interaction between Nafion and Several Trisbipyridyl Complexes by Spectroscopic Method[J]. Chinese Chemical Letters,
1997, 8(4): 357-360.
Citation: Yan Bing ZU, Pei Fang LIU, Chuan Sin CHA, Xi LI. Investigation of the Interaction between Nafion and Several Trisbipyridyl Complexes by Spectroscopic Method[J]. Chinese Chemical Letters, 1997, 8(4): 357-360.
Citation: Yan Bing ZU, Pei Fang LIU, Chuan Sin CHA, Xi LI. Investigation of the Interaction between Nafion and Several Trisbipyridyl Complexes by Spectroscopic Method[J]. Chinese Chemical Letters, 1997, 8(4): 357-360.
Investigation of the Interaction between Nafion and Several Trisbipyridyl Complexes by Spectroscopic Method
摘要:
In this paper,evidences of strong interaction between several tris-bipyridyl complexes and Nafion matrix are provided by UV-VIS and FTIR spectra.The studied counterions also show electrosiatic interaction with the bonded -SO3- groups,as indicated by the shifting of γSso3- to lower wave number.The most probable location of these complexes seems to be near the interface between the fluorocarbon back bone and the ionic cluster region.
English
Investigation of the Interaction between Nafion and Several Trisbipyridyl Complexes by Spectroscopic Method
Abstract:
In this paper,evidences of strong interaction between several tris-bipyridyl complexes and Nafion matrix are provided by UV-VIS and FTIR spectra.The studied counterions also show electrosiatic interaction with the bonded -SO3- groups,as indicated by the shifting of γSso3- to lower wave number.The most probable location of these complexes seems to be near the interface between the fluorocarbon back bone and the ionic cluster region.
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