引用本文:
Rui Fang GUAN, Chuan Jian ZHOU, Sheng Yu FENG, David J. BERG, Stephen R. STOBART. The Application of Suzuki Coupling Reaction on the Preparation of Carbosilane Dendrimers with 4-(Naphthalen-1-yl)phenyl Core[J]. Chinese Chemical Letters,
2006, 17(3): 293-295.
Citation: Rui Fang GUAN, Chuan Jian ZHOU, Sheng Yu FENG, David J. BERG, Stephen R. STOBART. The Application of Suzuki Coupling Reaction on the Preparation of Carbosilane Dendrimers with 4-(Naphthalen-1-yl)phenyl Core[J]. Chinese Chemical Letters, 2006, 17(3): 293-295.

Citation: Rui Fang GUAN, Chuan Jian ZHOU, Sheng Yu FENG, David J. BERG, Stephen R. STOBART. The Application of Suzuki Coupling Reaction on the Preparation of Carbosilane Dendrimers with 4-(Naphthalen-1-yl)phenyl Core[J]. Chinese Chemical Letters, 2006, 17(3): 293-295.

The Application of Suzuki Coupling Reaction on the Preparation of Carbosilane Dendrimers with 4-(Naphthalen-1-yl)phenyl Core
摘要:
Carbosilane dendrimers with p-bromophenyl core were synthesized by alternating Grignard and hydrosilylation reaction. And the α-naphthalenyl was connected to the core by the Suzuki coupling reaction. A new carbosilane dendrimer with big π-conjugated structure[4-(naphthalen-1-yl)phenyl core] was given. It shows Suzuki coupling reaction is an effective and powerful core-functionalization method and the satisfactory result can be obtained through prolonging the reaction time with the increase of the generation of dendrimer.
English
The Application of Suzuki Coupling Reaction on the Preparation of Carbosilane Dendrimers with 4-(Naphthalen-1-yl)phenyl Core
Abstract:
Carbosilane dendrimers with p-bromophenyl core were synthesized by alternating Grignard and hydrosilylation reaction. And the α-naphthalenyl was connected to the core by the Suzuki coupling reaction. A new carbosilane dendrimer with big π-conjugated structure[4-(naphthalen-1-yl)phenyl core] was given. It shows Suzuki coupling reaction is an effective and powerful core-functionalization method and the satisfactory result can be obtained through prolonging the reaction time with the increase of the generation of dendrimer.
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Key words:
- Suzuki coupling reaction
- / core functionalization
- / carbosilane
- / dendrimer
- / naphthalene

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