引用本文:
Ying Feng HAN, Ding Qiao YANG, Er Chang LIU, Jian Xia DONG. Rhodium-catalyzed Asymmetric Ring Opening Reaction of Oxabenzo-norbornadiene with Substituted Phenolic Nucleophiles[J]. Chinese Chemical Letters,
2006, 17(3): 296-298.
Citation: Ying Feng HAN, Ding Qiao YANG, Er Chang LIU, Jian Xia DONG. Rhodium-catalyzed Asymmetric Ring Opening Reaction of Oxabenzo-norbornadiene with Substituted Phenolic Nucleophiles[J]. Chinese Chemical Letters, 2006, 17(3): 296-298.
Citation: Ying Feng HAN, Ding Qiao YANG, Er Chang LIU, Jian Xia DONG. Rhodium-catalyzed Asymmetric Ring Opening Reaction of Oxabenzo-norbornadiene with Substituted Phenolic Nucleophiles[J]. Chinese Chemical Letters, 2006, 17(3): 296-298.
Rhodium-catalyzed Asymmetric Ring Opening Reaction of Oxabenzo-norbornadiene with Substituted Phenolic Nucleophiles
摘要:
We have developed an asymmetric ring opening reaction of oxabenzonorbornadienes with substituted phenolic nucleophiles. Under the reaction conditions ([Rh(COD)Cl]2 (1 mol%), (S)-(R)-PPF-ptBu2 (2 mol%), THF, reflux), the reaction products were obtained with high yield and enantiomeric excesses (up to 99% ee).
English
Rhodium-catalyzed Asymmetric Ring Opening Reaction of Oxabenzo-norbornadiene with Substituted Phenolic Nucleophiles
Abstract:
We have developed an asymmetric ring opening reaction of oxabenzonorbornadienes with substituted phenolic nucleophiles. Under the reaction conditions ([Rh(COD)Cl]2 (1 mol%), (S)-(R)-PPF-ptBu2 (2 mol%), THF, reflux), the reaction products were obtained with high yield and enantiomeric excesses (up to 99% ee).
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Key words:
- Asymmetric ring opening
- / rhodium-catalyzed
- / oxabenzonorbomadienes
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