Synthesis and Characterization of Ion-exchange Copolyimide

Li Rong ZHANG Chun Qing ZHANG Yan GAO Zhi Yuan JIA

引用本文: Li Rong ZHANG,  Chun Qing ZHANG,  Yan GAO,  Zhi Yuan JIA. Synthesis and Characterization of Ion-exchange Copolyimide[J]. Chinese Chemical Letters, 2004, 15(1): 17-18. shu
Citation:  Li Rong ZHANG,  Chun Qing ZHANG,  Yan GAO,  Zhi Yuan JIA. Synthesis and Characterization of Ion-exchange Copolyimide[J]. Chinese Chemical Letters, 2004, 15(1): 17-18. shu

Synthesis and Characterization of Ion-exchange Copolyimide

  • 基金项目:

    This project is supported by the National Natural Science Foundation of China (Contract grant number: 20104001).

摘要: A new diamine, disodium 4, 4'-di(4-aminophenoxy)-3, 3'-disulfonate-1, 1'-diphenyl-ketone, was prepared from the nucleophilic substitution of disodium 4, 4'-difluoro-3, 3'-di-sulfonate-1, 1'-diphenylketone and p-aminophenol. Polymerization of this diamine and 4, 4'-diamino-1, 1'-diphenyl ether with 3, 3', 4, 4'-tetracarboxyl dianhydride-1, 1'-diphenyl ketone gave ion-exchange copolyimide. The new diamine and its polyimide were characterized with 1H-NMR and FT-IR.

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  • 收稿日期:  2002-12-13
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