Stereospecifical Preparation of (E)-α-Stannyl-1-alkenylphosphonates and their Application in Stille Reaction

Zheng Chang XIONG Lu Ling WU Xian HUANG

引用本文: Zheng Chang XIONG,  Lu Ling WU,  Xian HUANG. Stereospecifical Preparation of (E)-α-Stannyl-1-alkenylphosphonates and their Application in Stille Reaction[J]. Chinese Chemical Letters, 2004, 15(1): 35-36. shu
Citation:  Zheng Chang XIONG,  Lu Ling WU,  Xian HUANG. Stereospecifical Preparation of (E)-α-Stannyl-1-alkenylphosphonates and their Application in Stille Reaction[J]. Chinese Chemical Letters, 2004, 15(1): 35-36. shu

Stereospecifical Preparation of (E)-α-Stannyl-1-alkenylphosphonates and their Application in Stille Reaction

摘要: The palladium catalyzed hydrostannation of 1-alkenylphosphonates gives the (E)-α-stannyl 1-alkenylphosphonates 2 stereospecifically. Compounds 2 can occur Stille coupling reaction to afford α, β-disubstituted vinylphosphonates with the retention of the configuration.

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  • 收稿日期:  2003-01-03
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