固相膜萃取-超声解吸-气相色谱-质谱法分析水中酞酸酯类化合物

引用本文: 李晓亚, 张永涛, 桂建业, 张辰凌, 张晶, 张莉. 固相膜萃取-超声解吸-气相色谱-质谱法分析水中酞酸酯类化合物[J]. 分析化学, 2017, 45(9): 1375-1380. doi: 10.11895/j.issn.0253-3820.170289 shu

Citation: LI Xiao-Ya, ZHANG Yong-Tao, GUI Jian-Ye, ZHANG Chen-Ling, ZHANG Jing, ZHANG Li. Solid Phase Membrane Extraction Combined with Ultrasonic Wave Desorption-Gas Chromatography-Mass Spectrometry for Analysis of Phthalate Esters in Water[J]. Chinese Journal of Analytical Chemistry, 2017, 45(9): 1375-1380. doi: 10.11895/j.issn.0253-3820.170289 shu

固相膜萃取-超声解吸-气相色谱-质谱法分析水中酞酸酯类化合物

中国地质科学院水文地质环境地质研究所监测中心, 正定 050803
基金项目:
本文系中国地质科学院基本科研业务费（No.YYWF201625）和国家自然科学基金（No.41302193）项目资助

摘要: 酞酸酯（PAEs）是一种常用的增塑剂，由于其广泛应用已经对环境造成了污染。本研究建立了固相膜萃取-超声解吸-气相色谱-质谱分析水中酞酸酯类化合物的方法。对萃取条件、解吸条件进行了优化，确定了最佳的实验条件。在水浴温度40℃，超声功率50%的条件下超声7 min，测定水中PAEs的检出限（S/N>3）在0.05~0.26 μg/L之间；对不同基质空白样品进行加标回收实验，回收率在76.2%~112.3%之间，相对标准偏差小于10%。

关键词:

English

Solid Phase Membrane Extraction Combined with Ultrasonic Wave Desorption-Gas Chromatography-Mass Spectrometry for Analysis of Phthalate Esters in Water

Institute of Hydrogeology and Environmental Geology, Chinese Academy of Geological Sciences, Zhengding 050803, China
Received Date: 07 May 2017
Revised Date: 20 June 2017
Fund Project:
This work was supported by the National Natural Science Foundation of China (No. 41302193).

Abstract: Phthalate esters (PAEs) are commonly used plasticizers and have caused pollution to the environment due to their widespread use. Therefore, many countries have listed such compounds as a priority list of pollutants, and it is of great significance to establish an accurate analysis method for monitoring the pollution of PAEs in water. A method of solid phase membrane extraction combined with ultrasonic wave desortion-gas chromatography-mass spectrometer for analysis of PAEs in water was established in this study. The extraction and desorb conditions were optimized. In this study, the samples were ultrasonic wave desorbed for 7 min at bath temperature of 40℃ and ultrasonic powder of 50%. The detection limits (S/N>3) of this method were between 0.05 μg/L and 0.26 μg/L, the recoveries in different matrixes were between 76.2% and 112.3%, and the relative standard deviations were below 10%.

Key words:

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沈阳化工大学材料科学与工程学院沈阳 110142

固相膜萃取-超声解吸-气相色谱-质谱法分析水中酞酸酯类化合物

English

Solid Phase Membrane Extraction Combined with Ultrasonic Wave Desorption-Gas Chromatography-Mass Spectrometry for Analysis of Phthalate Esters in Water

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

固相膜萃取-超声解吸-气相色谱-质谱法分析水中酞酸酯类化合物

English

Solid Phase Membrane Extraction Combined with Ultrasonic Wave Desorption-Gas Chromatography-Mass Spectrometry for Analysis of Phthalate Esters in Water

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

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CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs