引用本文:
An Pai LI, Hui WANG, Cheng Lu ZHANG, Tong Xing WU, Xin Fu PAN. First Total Synthesis of an Analogue of (±)-Hypargenin B[J]. Chinese Chemical Letters,
2002, 13(2): 133-134.
Citation: An Pai LI, Hui WANG, Cheng Lu ZHANG, Tong Xing WU, Xin Fu PAN. First Total Synthesis of an Analogue of (±)-Hypargenin B[J]. Chinese Chemical Letters, 2002, 13(2): 133-134.
Citation: An Pai LI, Hui WANG, Cheng Lu ZHANG, Tong Xing WU, Xin Fu PAN. First Total Synthesis of an Analogue of (±)-Hypargenin B[J]. Chinese Chemical Letters, 2002, 13(2): 133-134.
First Total Synthesis of an Analogue of (±)-Hypargenin B
摘要:
First total synthesis of (±)-hypargenin B methyl ether 2 was accomplished via a strategy of AC→ABC, in which CrO3/H2O/NaOAc/HOAc system was utilized for introducing 7-keto group in order to avoid dehydration of benzyl tertiary alcohol.
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关键词:
- Hypargenin B
- / diterpene
- / intramolecular
- / steroselective
English
First Total Synthesis of an Analogue of (±)-Hypargenin B
Abstract:
First total synthesis of (±)-hypargenin B methyl ether 2 was accomplished via a strategy of AC→ABC, in which CrO3/H2O/NaOAc/HOAc system was utilized for introducing 7-keto group in order to avoid dehydration of benzyl tertiary alcohol.
-
Key words:
- Hypargenin B
- / diterpene
- / intramolecular
- / steroselective
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