引用本文:
Yu Lan WANG, Yang Jie WU. Kinetics of Protonolysis of o-Substituted Phenylmercuric Chlorides by HCl(NaI) in Ethanol[J]. Chinese Chemical Letters,
1997, 8(4): 319-322.
Citation: Yu Lan WANG, Yang Jie WU. Kinetics of Protonolysis of o-Substituted Phenylmercuric Chlorides by HCl(NaI) in Ethanol[J]. Chinese Chemical Letters, 1997, 8(4): 319-322.
Citation: Yu Lan WANG, Yang Jie WU. Kinetics of Protonolysis of o-Substituted Phenylmercuric Chlorides by HCl(NaI) in Ethanol[J]. Chinese Chemical Letters, 1997, 8(4): 319-322.
Kinetics of Protonolysis of o-Substituted Phenylmercuric Chlorides by HCl(NaI) in Ethanol
摘要:
The kinetics of protonolysis of o-substituted phenylmercuric chlorides,o-XC6H4HgCl (X=H, CH3, CH3O, C2H5O, CF3, COOC2H5, Cl, Br, F, NO2), by hydrochloric acid in the presence of sodium iodide as catalyst have been studied in ethanol.The reaction has been found to be second order overall,first order in each reactant.The rate constants k measured at the same temperature may be arranged in the following order: C2H5O > CH3O > CH3 > H > CO2C2H5 > F > Cl > Br > CF3 > NO2.
English
Kinetics of Protonolysis of o-Substituted Phenylmercuric Chlorides by HCl(NaI) in Ethanol
Abstract:
The kinetics of protonolysis of o-substituted phenylmercuric chlorides,o-XC6H4HgCl (X=H, CH3, CH3O, C2H5O, CF3, COOC2H5, Cl, Br, F, NO2), by hydrochloric acid in the presence of sodium iodide as catalyst have been studied in ethanol.The reaction has been found to be second order overall,first order in each reactant.The rate constants k measured at the same temperature may be arranged in the following order: C2H5O > CH3O > CH3 > H > CO2C2H5 > F > Cl > Br > CF3 > NO2.
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