Citation:
FAN Guang, GUO Jin-Chan, LI Xiao-Bo, MA Zhan-Ying, DENG Ling-Juan, ZHANG Yin-Li. A 2D Cobalt(II) Coordination Polymer [Co(iqnc)2]n: Synthesis, Crystal Structure and Characterization[J]. Chinese Journal of Structural Chemistry,
2016, 34(10): 1612-1616.
doi:
10.14102/j.cnki.0254-5861.2011-0708
A 2D Cobalt(II) Coordination Polymer [Co(iqnc)2]n: Synthesis, Crystal Structure and Characterization
摘要:
A new cobalt(II) coordination polymer with the formula of [Co(iqnc)2]n (1, iqnc=l-isoquinolinecarboxylate) has been synthesized through hydrothermal synthesis and structurally characterized by single-crystal X-ray diffraction method. The title coordination polymer represents a two-dimensional layer structure featuring adjacent one-dimensional [Co(iqnc)2]n chains connected with each other by uncoordinated oxygen atoms of carboxylate. Crystal data: monoclinic, space group P21/c, a=15.4302(2), b=5.6743(7), c=9.2307(1) Å, β=98.459(2)°, V=799.41(2) Å3, Z=2, S=1.019, the final R=0.0346, wR=0.0876 (I>2σ(I)) and R=0.0477 and wR=0.1159 for all reflections. In addition, elemental analysis, IR, and magnetism properties are presented.
English
A 2D Cobalt(II) Coordination Polymer [Co(iqnc)2]n: Synthesis, Crystal Structure and Characterization
Abstract:
A new cobalt(II) coordination polymer with the formula of [Co(iqnc)2]n (1, iqnc=l-isoquinolinecarboxylate) has been synthesized through hydrothermal synthesis and structurally characterized by single-crystal X-ray diffraction method. The title coordination polymer represents a two-dimensional layer structure featuring adjacent one-dimensional [Co(iqnc)2]n chains connected with each other by uncoordinated oxygen atoms of carboxylate. Crystal data: monoclinic, space group P21/c, a=15.4302(2), b=5.6743(7), c=9.2307(1) Å, β=98.459(2)°, V=799.41(2) Å3, Z=2, S=1.019, the final R=0.0346, wR=0.0876 (I>2σ(I)) and R=0.0477 and wR=0.1159 for all reflections. In addition, elemental analysis, IR, and magnetism properties are presented.
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