SYNTHESIS OF 3-BENZYL-GLYCERIC ACID:A KEY INTERMEDIATE OF A NOVEL CYCLIC ESTER MONOMER*

Citation:   SYNTHESIS OF 3-BENZYL-GLYCERIC ACID:A KEY INTERMEDIATE OF A NOVEL CYCLIC ESTER MONOMER*[J]. Chinese Journal of Polymer Science, 2002, 20(2): 177-180. shu

SYNTHESIS OF 3-BENZYL-GLYCERIC ACID:A KEY INTERMEDIATE OF A NOVEL CYCLIC ESTER MONOMER*

摘要: A route was proposed to synthesize 3-benryl-glyceric acid (3-BGA) as an important intermediate for the synthesis ofa novel six-membered cyclic ester monomer - 3-benzyloxymethyl-1,4-dioxane-2,5-dione (3-BMG). According to this route,3-BGA was obtained from ring-opening reaction of benzyl alcohol with methyl glycidate, which was prepared from theepoxidation of methyl acrylate using sodium hypochlorite as the oxidant.

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  • 发布日期:  2002-04-20
  • 收稿日期:  2001-10-19
  • 修回日期:  2001-11-23
通讯作者: 陈斌, bchen63@163.com
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    沈阳化工大学材料科学与工程学院 沈阳 110142

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