Citation:
LI Huan-Huan, LIU Li, MING Chun-Lun, CUI Guang-Hua. Synthesis and Characterization of a Two-dimensional Cadmium(Ⅱ) Metal Organic Framework with Fes Topology[J]. Chinese Journal of Structural Chemistry,
2014, 33(7): 1050-1056.
Synthesis and Characterization of a Two-dimensional Cadmium(Ⅱ) Metal Organic Framework with Fes Topology
摘要:
A new Cd(Ⅱ) coordination polymer, {[Cd(Hnbta)(L)]·H2O}n (L=1,4-bis(5,6-dimethylbenzimidazol-1-yl)butane), H3nbta=5-nitrobenzene-1,2,3-tricarboxylic acid), has been hydro-thermally synthesized and characterized by elemental analyses, IR, XRPD, and single-crystal X-ray diffraction. The title compound crystallizes in the monoclinic system, space group P21/n with a=17.3056(13), b=11.0114(9), c=17.7484(14) Å, β=117.3640(10)°, V=3003.7(4) Å3, Z=4, C31H31CdN5O9, Mr=730.01, Dc=1.614 g/cm3, μ=0.792 mm-1 and F(000)=1488. The cadmium(Ⅱ) ions are bridged by Hnbta2- to generate a two-dimensional metal organic framework with fes topology. In addition, the thermal stability and fluorescence properties of the complex were also studied.
English
Synthesis and Characterization of a Two-dimensional Cadmium(Ⅱ) Metal Organic Framework with Fes Topology
Abstract:
A new Cd(Ⅱ) coordination polymer, {[Cd(Hnbta)(L)]·H2O}n (L=1,4-bis(5,6-dimethylbenzimidazol-1-yl)butane), H3nbta=5-nitrobenzene-1,2,3-tricarboxylic acid), has been hydro-thermally synthesized and characterized by elemental analyses, IR, XRPD, and single-crystal X-ray diffraction. The title compound crystallizes in the monoclinic system, space group P21/n with a=17.3056(13), b=11.0114(9), c=17.7484(14) Å, β=117.3640(10)°, V=3003.7(4) Å3, Z=4, C31H31CdN5O9, Mr=730.01, Dc=1.614 g/cm3, μ=0.792 mm-1 and F(000)=1488. The cadmium(Ⅱ) ions are bridged by Hnbta2- to generate a two-dimensional metal organic framework with fes topology. In addition, the thermal stability and fluorescence properties of the complex were also studied.
-
-
扫一扫看文章
计量
- PDF下载量: 0
- 文章访问数: 1388
- HTML全文浏览量: 8
下载:
