Citation:
YANG Hua, HU Dao-Dao. Synthesis, Structure, and Luminescent Property of a 3-D Zinc Complex {[Zn8Ⅱ(4-APha)8(CH3COO)8](CH3CH2OH)2}n[J]. Chinese Journal of Structural Chemistry,
2014, 33(7): 1019-1024.
Synthesis, Structure, and Luminescent Property of a 3-D Zinc Complex {[Zn8Ⅱ(4-APha)8(CH3COO)8](CH3CH2OH)2}n
摘要:
The title complex [Zn8Ⅱ(4-APha)8(CH3COO)8(CH3CH2OH)2]n (1, 4-APha=4-aminophenylhydroxamic acid) has been prepared under solvothermal conditions. It has been characterized by X-ray single-crystal diffraction, IR and elemental analysis. The crystal belongs to the monoclinic system, space group C2/c with a=39.074(4), b=9.9645(8), c=38.846(3) Å, β=136.438°, V=10423.1(14) Å3, C84H118N16O39Zn8, Mr=2498.90, Z=4, Dc=1.592 g/cm3, μ=1.900 mm-1, F(000)=5144, the final R=0.1036 and wR=0.2953. This complex possesses a 3-D structure which is constructed from 1-D chain motifs linked by the 4-APha- ligands. The luminescent property of the title complex has been investigated.
English
Synthesis, Structure, and Luminescent Property of a 3-D Zinc Complex {[Zn8Ⅱ(4-APha)8(CH3COO)8](CH3CH2OH)2}n
Abstract:
The title complex [Zn8Ⅱ(4-APha)8(CH3COO)8(CH3CH2OH)2]n (1, 4-APha=4-aminophenylhydroxamic acid) has been prepared under solvothermal conditions. It has been characterized by X-ray single-crystal diffraction, IR and elemental analysis. The crystal belongs to the monoclinic system, space group C2/c with a=39.074(4), b=9.9645(8), c=38.846(3) Å, β=136.438°, V=10423.1(14) Å3, C84H118N16O39Zn8, Mr=2498.90, Z=4, Dc=1.592 g/cm3, μ=1.900 mm-1, F(000)=5144, the final R=0.1036 and wR=0.2953. This complex possesses a 3-D structure which is constructed from 1-D chain motifs linked by the 4-APha- ligands. The luminescent property of the title complex has been investigated.
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Key words:
- zinc complex
- / hydroxamic acids
- / 3-D framework
- / luminescent property
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