Citation:
GAO Yu-Jiao, DENG Xiao-Yan, PENG Hao, HE Hong-Wu. Synthesis, Characterization and X-ray Crystal Structure of 2-Methylpropan-2-aminium Methyl ((4-Fluorobenzamido) (4-fluorophenyl)methyl)phosphonate·H2O[J]. Chinese Journal of Structural Chemistry,
2014, 33(7): 985-989.
Synthesis, Characterization and X-ray Crystal Structure of 2-Methylpropan-2-aminium Methyl ((4-Fluorobenzamido) (4-fluorophenyl)methyl)phosphonate·H2O
摘要:
A new crystal of 2-methylpropan-2-aminium methyl ((4-fluorobenzamido)(4-fluorophenyl)methyl)phosphonate has been prepared at room temperature and characterized by 1HNMR, 13C NMR, IR, MS, elemental analysis and X-ray single-crystal determination. The compound crystallizes in monoclinic space group C2/c with a=20.719(2), b=11.8559(13), c=18.176(2) Å, β=94.434(2)°, V=4451.4(9) Å3, Dc=1.317 Mg/m3, Z=8, F(000)=1864 and μ=0.174 mm-1. The crystal packing is stabilized by intermolecular N-H…O and O-H…O hydrogen bonds, as well as by weak π-π stacking interactions.
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关键词:
- X-ray crystallography
- / benzamide
- / phosphonate
English
Synthesis, Characterization and X-ray Crystal Structure of 2-Methylpropan-2-aminium Methyl ((4-Fluorobenzamido) (4-fluorophenyl)methyl)phosphonate·H2O
Abstract:
A new crystal of 2-methylpropan-2-aminium methyl ((4-fluorobenzamido)(4-fluorophenyl)methyl)phosphonate has been prepared at room temperature and characterized by 1HNMR, 13C NMR, IR, MS, elemental analysis and X-ray single-crystal determination. The compound crystallizes in monoclinic space group C2/c with a=20.719(2), b=11.8559(13), c=18.176(2) Å, β=94.434(2)°, V=4451.4(9) Å3, Dc=1.317 Mg/m3, Z=8, F(000)=1864 and μ=0.174 mm-1. The crystal packing is stabilized by intermolecular N-H…O and O-H…O hydrogen bonds, as well as by weak π-π stacking interactions.
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Key words:
- X-ray crystallography
- / benzamide
- / phosphonate
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