注册 English

Ca(Ⅱ)、Mg(Ⅱ)和 Zn(Ⅱ)与丙二醇-水混合体系中L-多巴的二元配合物的生成平衡

Santhee Devi K V ,  Ramaraju B ,  Nageswara Rao G

downloadPDF
引用本文: Santhee Devi K V, Ramaraju B, Nageswara Rao G. Ca(Ⅱ)、Mg(Ⅱ)和 Zn(Ⅱ)与丙二醇-水混合体系中L-多巴的二元配合物的生成平衡[J]. 无机化学学报, 2013, 29(6): 1235-1242. doi: 10.3969/j.issn.1001-4861.2013.00.180 shu
Citation:  Santhee Devi K V, Ramaraju B, Nageswara Rao G. Binary Complex Formation Equilibria of Ca(Ⅱ), Mg(Ⅱ) and Zn(Ⅱ) with L-dopa in Propylene Glycol-Water Mixtures[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(6): 1235-1242. doi: 10.3969/j.issn.1001-4861.2013.00.180 shu

Ca(Ⅱ)、Mg(Ⅱ)和 Zn(Ⅱ)与丙二醇-水混合体系中L-多巴的二元配合物的生成平衡

摘要: 在303 K恒温条件下,以NaCl为电解质保持离子强度为0.16 mol·L-1,用pH滴定法研究了M(Ⅱ)-Dopa(多巴)二元配合物在0～60%(V/V)的丙二醇(PG)-水体系中的生成平衡。在PG-水体系中,Ca(Ⅱ)和Mg(Ⅱ)的典型配合物为MLH,ML2,ML2H和ML2H2,而Zn(Ⅱ)的典型配合物为ML,MLH,ML2,ML2H和ML2H2。根据静电和非静电力解释了稳定常数随介质的介电常数而变化的倾向。还讨论了在不同组成的丙二醇(PG)-水体系中配合物物种随pH值变化的情况。

English

  • 

    1. [1] Lavanya KV, Rao V M, Rao G N. Oxidat. Commun., 2008, 31:398-409[1] Lavanya KV, Rao V M, Rao G N. Oxidat. Commun., 2008, 31:398-409

    2. [2] Latha M P, Rao V M, Rao T S, et al. Bull. Chem. Soc. Ethiop., 2007,21:363-372[2] Latha M P, Rao V M, Rao T S, et al. Bull. Chem. Soc. Ethiop., 2007,21:363-372

    3. [3] Rao G N, Ramakrishna A. Proc. Nat. Acad. Sci. India, 2005, 75:245-248[3] Rao G N, Ramakrishna A. Proc. Nat. Acad. Sci. India, 2005, 75:245-248

    4. [4] Rao G N, Sudarsan K G. Chem. Speciat. Bioavail., 2006,18: 71-76[4] Rao G N, Sudarsan K G. Chem. Speciat. Bioavail., 2006,18: 71-76

    5. [5] May P M, Linder P W, Williams D R. Dalton Trans., 1977: 588-595[5] May P M, Linder P W, Williams D R. Dalton Trans., 1977: 588-595

    6. [6] Gergely A, Kiss T, Deak G. Inorg. Chim. Acta, 1979,36:113- 120[6] Gergely A, Kiss T, Deak G. Inorg. Chim. Acta, 1979,36:113- 120

    7. [7] Kiss T, Defik G, Gergely A. Inorg. Chim. Acta, 1984,91:269 -277[7] Kiss T, Defik G, Gergely A. Inorg. Chim. Acta, 1984,91:269 -277

    8. [8] Watanabe S, Saito T. J. Inorg. Biochem., 1995,58:147-155[8] Watanabe S, Saito T. J. Inorg. Biochem., 1995,58:147-155

    9. [9] Rajan K S, Mainer S. Bioinorg. Chem., 1978,9:187-203[9] Rajan K S, Mainer S. Bioinorg. Chem., 1978,9:187-203

    10. [10] Damodaran N, Ramaswamy R. Biochem. J., 1937,31:2149- 2152[10] Damodaran N, Ramaswamy R. Biochem. J., 1937,31:2149- 2152

    11. [11] Birkmayer W, Horneykiewicz O. Wien. Klin. Wschr., 1961, 73:787-788[11] Birkmayer W, Horneykiewicz O. Wien. Klin. Wschr., 1961, 73:787-788

    12. [12] Horneykiewicz O. Wien. Klin. Wschr., 1963,75:309-312[12] Horneykiewicz O. Wien. Klin. Wschr., 1963,75:309-312

    13. [13] Mena J, Court J, Fuenzalida S, et al. New Eng. J. Med., 1970,282:5-10[13] Mena J, Court J, Fuenzalida S, et al. New Eng. J. Med., 1970,282:5-10

    14. [14] Flanagan R J, Braithwaite R, Brown S S, et al. Basic Analytical Toxicology, Avenue Appia 20, 1211 Geneva 27 (WHO), Switzerland, 1995.[14] Flanagan R J, Braithwaite R, Brown S S, et al. Basic Analytical Toxicology, Avenue Appia 20, 1211 Geneva 27 (WHO), Switzerland, 1995.

    15. [15] National Library of Medicine; Propylene Glycol Is Used in Antifreezes Human Toxicity Excerpts: CAS Registry Number: 57-55-6 (Propylene Glycol). Selected Toxicity Information from HSDB. 2005.[15] National Library of Medicine; Propylene Glycol Is Used in Antifreezes Human Toxicity Excerpts: CAS Registry Number: 57-55-6 (Propylene Glycol). Selected Toxicity Information from HSDB. 2005.

    16. [16] Weaver C M, Heaney R P, Modern Nutrition in Health and Disease. 10th Ed. Shils M E, Shike M, Ross A C, et al. (Eds.) Lippincott Williams & Wilkins, 2006:194-210[16] Weaver C M, Heaney R P, Modern Nutrition in Health and Disease. 10th Ed. Shils M E, Shike M, Ross A C, et al. (Eds.) Lippincott Williams & Wilkins, 2006:194-210

    17. [17] Riggs B L, Melton L, Bone, 1995,17:505S-511S[17] Riggs B L, Melton L, Bone, 1995,17:505S-511S

    18. [18] Wester P O. Am. J. Clin. Nutr., 1987,45:1305-1312[18] Wester P O. Am. J. Clin. Nutr., 1987,45:1305-1312

    19. [19] Saris N E, Mervaala E, Karppanen H, et al. Clin. Chim. Acta, 2000,294:1-26[19] Saris N E, Mervaala E, Karppanen H, et al. Clin. Chim. Acta, 2000,294:1-26

    20. [20] Sandstead H. J. Lab. Clin. Med., 1994,124:322-327[20] Sandstead H. J. Lab. Clin. Med., 1994,124:322-327

    21. [21] Solomons N W. Nutr. Rev., 1998,56:27-28[21] Solomons N W. Nutr. Rev., 1998,56:27-28

    22. [22] Prasad A S. Nutrition, 1995,11:93-99[22] Prasad A S. Nutrition, 1995,11:93-99

    23. [23] Heyneman C A. Ann. Pharmacother, 1996,30:186-7[23] Heyneman C A. Ann. Pharmacother, 1996,30:186-7

    24. [24] Taylor A. Ann. Clin. Biochem., 1996,33:486-510[24] Taylor A. Ann. Clin. Biochem., 1996,33:486-510

    25. [25] Taylor A. Ann. Clin. Biochem., 1997,34:142-50[25] Taylor A. Ann. Clin. Biochem., 1997,34:142-50

    26. [26] Murphy J V. JAMA, 1970,212:2119-20[26] Murphy J V. JAMA, 1970,212:2119-20

    27. [27] Prody C I, Holland N R. Neurology, 2000,54:1705-1706[27] Prody C I, Holland N R. Neurology, 2000,54:1705-1706

    28. [28] Vallee B L. Biofactors, 1988,1:31-36[28] Vallee B L. Biofactors, 1988,1:31-36

    29. [29] Rao R S, Rao G N. Computer Applications in Chemistry. Mumbai: Himalaya Publishing House, 2005:277-352[29] Rao R S, Rao G N. Computer Applications in Chemistry. Mumbai: Himalaya Publishing House, 2005:277-352

    30. [30] Gran G. Analyst, 1952,77:661-671[30] Gran G. Analyst, 1952,77:661-671

    31. [31] Gran G. Anal. Chim. Acta, 1988,206:111-123[31] Gran G. Anal. Chim. Acta, 1988,206:111-123

    32. [32] Latha M P, Rao V M, Rao T S, et al. Bull. Chem. Soc. Ethiop., 2007,21:363-372[32] Latha M P, Rao V M, Rao T S, et al. Bull. Chem. Soc. Ethiop., 2007,21:363-372

    33. [33] Padmaja N, Babu M S, Rao G N, et al. J. Indian Chem. Soc., 1990,81:384-387[33] Padmaja N, Babu M S, Rao G N, et al. J. Indian Chem. Soc., 1990,81:384-387

    34. [34] Rao G N. Ph. D. Thesis, Andhra University, Visakhapatnam, India, 1989.[34] Rao G N. Ph. D. Thesis, Andhra University, Visakhapatnam, India, 1989.

    35. [35] Gans P, Sabatini A, Vacca A. Inorg. Chim. Acta, 1976,18: 237-239[35] Gans P, Sabatini A, Vacca A. Inorg. Chim. Acta, 1976,18: 237-239

    36. [36] Born M. Z. Phys., 1920,1:45-57[36] Born M. Z. Phys., 1920,1:45-57

  • 加载中
WeChat 扫一扫看文章
计量
  • PDF下载量:  461
  • 文章访问数:  561
  • HTML全文浏览量:  41
文章相关
  • 收稿日期:  2013-01-01
  • 网络出版日期:  2013-03-02
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章

All Rights Reserved by the Chinese Chemical Society   中国化学会 版权所有 京ICP备05002797号

本系统由北京仁和汇智信息技术有限公司开发    技术支持: info@rhhz.net