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基于对苯二甲酸根及邻菲咯啉的铁(Ⅱ)配位聚合物的水热合成、晶体结构和荧光性质

陈书阳 ,  赵伟 ,  郭应臣

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引用本文: 陈书阳, 赵伟, 郭应臣. 基于对苯二甲酸根及邻菲咯啉的铁(Ⅱ)配位聚合物的水热合成、晶体结构和荧光性质[J]. 无机化学学报, 2013, 29(6): 1165-1170. doi: 10.3969/j.issn.1001-4861.2013.00.201 shu
Citation:  CHEN Shu-Yang, ZHAO Wei, GUO Ying-Chen. Hydrothermal Synthesis, Crystal Structure and Luminescence of a Iron Coordination Polymer with Terephthalate and o-Phenanthroline[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(6): 1165-1170. doi: 10.3969/j.issn.1001-4861.2013.00.201 shu

基于对苯二甲酸根及邻菲咯啉的铁(Ⅱ)配位聚合物的水热合成、晶体结构和荧光性质

  • 基金项目:

    河南省教育厅自然科学基金(No.2011B150025)资助项目。 (No.2011B150025)

摘要: 以对苯二甲酸(H2bdc)、邻菲咯啉(phen)和硫酸亚铁为原料,在水热条件下合成了一个新的配位聚合物[Fe(phen)(bdc)(H2O)]n,并对其进行了元素分析、红外光谱、紫外-可见光谱、热重和X-射线单晶衍射表征。该聚合物属于三斜晶系,P1空间群。每个Fe(Ⅱ)与2个N原子和3个O原子配位形成高度畸变的三角双锥结构,2个Fe(Ⅱ)由配体对苯二甲酸离子桥联为一维链状结构,链与链之间通过O-H…O氢键作用形成三维结构。荧光测试表明配合物在368 nm处有荧光发射。

English

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  • 收稿日期:  2012-08-12
  • 网络出版日期:  2013-02-12
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