注册 English

大孔MgO/ZrO2固体碱的制备及催化性能

尹锡俊 ,  龙能兵 ,  张祥洲 ,  侯琳熙

downloadPDF
引用本文: 尹锡俊, 龙能兵, 张祥洲, 侯琳熙. 大孔MgO/ZrO2固体碱的制备及催化性能[J]. 无机化学学报, 2013, 29(4): 739-746. doi: 10.3969/j.issn.1001-4861.2013.00.098 shu
Citation:  YIN Xi-Jun, LONG Neng-Bing, ZHANG Xiang-Zhou, HOU Lin-Xi. Preparation and Catalytic Property of Macroporous MgO/ZrO2 Composite Catalyst[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(4): 739-746. doi: 10.3969/j.issn.1001-4861.2013.00.098 shu

大孔MgO/ZrO2固体碱的制备及催化性能

  • 基金项目:

    浙江省教育厅2012年度科研计划项目(No.Y201223742) (No.Y201223742)

    宁波大学王宽诚幸福基金资助项目。 

摘要: 以多孔聚合物为整体型模板, 利用锆酸四丁酯原位水解并结合高温烧结的方法制备出大孔ZrO2载体, 通过Mg(NO3)2溶液浸渍、高温煅烧制备出大孔MgO/ZrO2复合材料。SEM、FTIR、XRD、TG-DSC表征发现ZrO2载体是由三维连续的纳米薄层构成的大孔材料, MgO以纳米颗粒形式沉积在ZrO2的三维超薄层上。进一步通过CO2-TPD手段发现该ZrO2表面具有弱碱性位, MgO的负载显著增加了复合物的碱性。以碳酸二甲酯和异辛醇酯交换合成碳酸二异辛酯为探针反应, 考察焙烧温度及活性组分负载量等制备条件对大孔MgO/ZrO2固体碱催化活性的影响。结果表明, 该催化剂对碳酸二异辛酯的合成具有较好的催化活性, 当焙烧温度为600℃, MgO含量为50%时目标产物的产率可高达到65%。

English

  • 

    1. [1] Sizgek G D, Sizgek E, Griffith C S, et al. Langmuir, 2008,24 (21):12323-12330[1] Sizgek G D, Sizgek E, Griffith C S, et al. Langmuir, 2008,24 (21):12323-12330

    2. [2] Drisko G L, Luca V, Sizgek E, et al. Langmuir, 2009,25(9): 5286-5293[2] Drisko G L, Luca V, Sizgek E, et al. Langmuir, 2009,25(9): 5286-5293

    3. [3] Li H N, Zhang L, Dai H X, et al. Inorg. Chem., 2009,48(10): 4421-4434[3] Li H N, Zhang L, Dai H X, et al. Inorg. Chem., 2009,48(10): 4421-4434

    4. [4] CUI Xiao-Yan(崔晓燕), DENG Wei(邓威). Chinese J. Chem. Adhe.(Huaxue Yu Nianhe), 2011,33(3):53-56[4] CUI Xiao-Yan(崔晓燕), DENG Wei(邓威). Chinese J. Chem. Adhe.(Huaxue Yu Nianhe), 2011,33(3):53-56

    5. [5] LI Ting(李婷). Thesis for the Master of Harbin Technology University(哈尔滨工业大学硕士论文). 2011.[5] LI Ting(李婷). Thesis for the Master of Harbin Technology University(哈尔滨工业大学硕士论文). 2011.

    6. [6] Tian X K, Zeng Y L, Xiao T, et al. Microp. Mesop. Mater., 2011,143:357-361[6] Tian X K, Zeng Y L, Xiao T, et al. Microp. Mesop. Mater., 2011,143:357-361

    7. [7] Ding Y Q, Sun H, Duan J Z, et al. Catal. Commun., 2011, 12:606-610[7] Ding Y Q, Sun H, Duan J Z, et al. Catal. Commun., 2011, 12:606-610

    8. [8] Kitada A, Hasegawa G, Kobayash Y, et al. J. Am. Chem. Soc., 2012,134(26):10894-10898[8] Kitada A, Hasegawa G, Kobayash Y, et al. J. Am. Chem. Soc., 2012,134(26):10894-10898

    9. [9] Drisko G L, Cao L, Kimling M C, et al. Appl. Mater. Interfaces, 2009,1(12):2893-2901[9] Drisko G L, Cao L, Kimling M C, et al. Appl. Mater. Interfaces, 2009,1(12):2893-2901

    10. [10] Pablo M A, Massimiliano C, Ferdi S, et al. Angew. Chem. Int. Ed., 2006,45(48):8224-8227[10] Pablo M A, Massimiliano C, Ferdi S, et al. Angew. Chem. Int. Ed., 2006,45(48):8224-8227

    11. [11] SHEN Yong(沈勇), WU Quan-Zhou(邬泉周), LI Yu-Guang (李玉光), et al. Acta Physico-Chimica Sinica(Wuli Huaxue Xuebao), 2006,22(9):1121-1125[11] SHEN Yong(沈勇), WU Quan-Zhou(邬泉周), LI Yu-Guang (李玉光), et al. Acta Physico-Chimica Sinica(Wuli Huaxue Xuebao), 2006,22(9):1121-1125

    12. [12] MA Fu(马富), LI Yun(李云), LUO Shi-Jie(罗时杰), et al. Chinese J. Rare Earths(Zhongguo Xitu Xuebao), 2006,24: 35-37[12] MA Fu(马富), LI Yun(李云), LUO Shi-Jie(罗时杰), et al. Chinese J. Rare Earths(Zhongguo Xitu Xuebao), 2006,24: 35-37

    13. [13] SUN Rui-Qin(孙瑞琴), ZHOU Xu(周徐), SUN Lin-Bing(孙 林兵), et al. Chem. J. Chinese Universities(Gaodeng Xuexiao Huaxue Xuebao), 2007,28(12):2333-2337[13] SUN Rui-Qin(孙瑞琴), ZHOU Xu(周徐), SUN Lin-Bing(孙 林兵), et al. Chem. J. Chinese Universities(Gaodeng Xuexiao Huaxue Xuebao), 2007,28(12):2333-2337

    14. [14] WEI Yi-Lun(魏一伦), CAO Yi(曹毅), ZHU Jian-Hua(朱建 华), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2003,19(3):233-238[14] WEI Yi-Lun(魏一伦), CAO Yi(曹毅), ZHU Jian-Hua(朱建 华), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2003,19(3):233-238

    15. [15] Liu S G, Huang S Y, Guan L X, et al. Microp. Mesop. Mater., 2007,102:304-309[15] Liu S G, Huang S Y, Guan L X, et al. Microp. Mesop. Mater., 2007,102:304-309

    16. [16] Liu S G, Ma J, Guan L X, et al. Microp. Mesop. Mater., 2009,117:466-471[16] Liu S G, Ma J, Guan L X, et al. Microp. Mesop. Mater., 2009,117:466-471

    17. [17] Zhang R F, Zhang L L. Polym. Bull., 2008,61:671-677[17] Zhang R F, Zhang L L. Polym. Bull., 2008,61:671-677

    18. [18] LONG Neng-Bing(龙能兵), ZHANG Rui-Feng(张瑞丰). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2009,25(7): 1153-1158[18] LONG Neng-Bing(龙能兵), ZHANG Rui-Feng(张瑞丰). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2009,25(7): 1153-1158

    19. [19] LONG Neng-Bing(龙能兵), WANG Qiu-jin(王秋景), ZHANG Rui-Feng(张瑞丰). Acta. Mater. Comp. Sin.(Fuhe Cailiao Xuebao), 2011,28(5):119-125[19] LONG Neng-Bing(龙能兵), WANG Qiu-jin(王秋景), ZHANG Rui-Feng(张瑞丰). Acta. Mater. Comp. Sin.(Fuhe Cailiao Xuebao), 2011,28(5):119-125

    20. [20] HOU Lin-Xi(侯琳熙), YIN Xi-Jun(尹锡俊), LONG Neng- Bing(龙能兵). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(2):239-244[20] HOU Lin-Xi(侯琳熙), YIN Xi-Jun(尹锡俊), LONG Neng- Bing(龙能兵). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(2):239-244

  • 加载中
WeChat 扫一扫看文章
计量
  • PDF下载量:  250
  • 文章访问数:  654
  • HTML全文浏览量:  44
文章相关
  • 收稿日期:  2012-10-06
  • 网络出版日期:  2012-11-28
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章

All Rights Reserved by the Chinese Chemical Society   中国化学会 版权所有 京ICP备05002797号

本系统由北京仁和汇智信息技术有限公司开发    技术支持: info@rhhz.net