LiYF4晶体中Ho3+离子真空紫外吸收光谱的理论解析

李彩云 王永明

引用本文: 李彩云, 王永明. LiYF4晶体中Ho3+离子真空紫外吸收光谱的理论解析[J]. 无机化学学报, 2013, 29(4): 735-738. doi: 10.3969/j.issn.1001-4861.2013.00.136 shu
Citation:  LI Cai-Yun, WANG Yong-Ming. Theoretical Analyses of Vacuum Ultraviolet Absorption Spectra of Ho3+ Doped in LiYF4 Crystal[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(4): 735-738. doi: 10.3969/j.issn.1001-4861.2013.00.136 shu

LiYF4晶体中Ho3+离子真空紫外吸收光谱的理论解析

摘要: 运用配位场理论方法获得了Ho3+离子低自旋4f95d组态的谱项和J-光谱多重态, 根据电偶极跃迁选律合理地解析了LiYF4晶体中Ho3+离子在真空紫外区(120~160 nm)的吸收光谱, 4个主要的吸收峰分别被归属为从基态(5I8)到Ho3+离子的低自旋4f95d组态的自旋允许跃迁。

English

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  • 收稿日期:  2012-10-19
  • 网络出版日期:  2012-11-27
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