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TiO2纳米管阵列负载不同形貌Cu2O薄膜的制备及光电性能研究

薛晋波 ,  申倩倩 ,  李光亮 ,  梁伟

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引用本文: 薛晋波, 申倩倩, 李光亮, 梁伟. TiO2纳米管阵列负载不同形貌Cu2O薄膜的制备及光电性能研究[J]. 无机化学学报, 2013, 29(4): 729-734. doi: 10.3969/j.issn.1001-4861.2013.00.120 shu
Citation:  XUE Jin-Bo, SHEN Qian-Qian, LI Guang-Liang, LIANG Wei. Preparation and Photoelectric Property of Different Morphologies Cu2O Loaded on TiO2 Nanotube Arrays Films[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(4): 729-734. doi: 10.3969/j.issn.1001-4861.2013.00.120 shu

TiO2纳米管阵列负载不同形貌Cu2O薄膜的制备及光电性能研究

  • 基金项目:

    国家自然科学基金(No.51175363, No. 51274149) (No.51175363, No. 51274149)

    长江学者与创新团队发展计划(IRT0972) (IRT0972)

    校科技发展基金(K2010016) 资助项目。 (K2010016)

摘要: 本论文采用阳极氧化法在金属钛基底上制备高度有序的TiO2纳米管阵列薄膜, 然后采用脉冲电流法在TiO2纳米管阵列上沉积Cu2O, 从而制备出Cu2O-TiO2纳米管阵列异质结复合薄膜。借助X射线衍射仪(XRD), 场发射扫描电子显微镜(FESEM)和透射电子显微镜(TEM)等表征手段, 详细探讨了Cu2O沉积过程中电解液的不同扰动方式(静止、磁力搅拌和超声搅拌)对复合薄膜物相和形貌的影响。实验结果表明电解液的扰动方式会影响Cu2O沉积过程中的离子扩散和微区化学环境, 从而影响Cu2O的形貌。通过漫反射紫外-可见吸收光谱(UV-Vis)和光电流性能测试可知所制备的负载Cu2O型TiO2纳米管阵列薄膜具有显著的可见光响应效应。

English

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  • 收稿日期:  2012-09-06
  • 网络出版日期:  2013-01-04
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