间苯二乙酸构筑的2D锰(Ⅱ)配合物的合成及晶体结构

引用本文: 张美丽, 张钢强, 王记江, 任宜霞, 陈小利, 吕磊. 间苯二乙酸构筑的2D锰(Ⅱ)配合物的合成及晶体结构[J]. 无机化学学报, 2013, 29(4): 671-676. doi: 10.3969/j.issn.1001-4861.2013.00.146 shu

Citation: ZHANG Mei-Li, ZHANG Gang-Qiang, WANG Ji-Jiang, REN Yi-Xia, CHEN Xiao-Li, LÜ Lei. Synthesis and Crystal Structure of 2D Mn(Ⅱ) Complex with Flexible Phenylenediacetic Ligand[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(4): 671-676. doi: 10.3969/j.issn.1001-4861.2013.00.146 shu

间苯二乙酸构筑的2D锰(Ⅱ)配合物的合成及晶体结构

张美丽 ^1, ,
张钢强 ^2, ,
王记江 ^1, ,
任宜霞 ^1, ,
陈小利 ^1, ,
吕磊 ^1,

基金项目:
陕西省教育厅科研基金(No.11JK0567, 11JK0565, 12JK0636) (No.11JK0567, 11JK0565, 12JK0636)

延安大学自然基金(No.YDZD2011-07)资助项目。 (No.YDZD2011-07)

摘要: 利用柔性配体合成了配合物[Mn(pda)(bpp)] (1)(H₂pda=1, 3-phenylenediacetic acid, bpp=1, 3-bi(4-pyridyl)propane), 并对其进行了元素分析、红外光谱和X 射线单晶衍射测定。配合物1属于正交晶系, 空间群为Pnna, a=1.965 2(6) nm, b=1.103 3(4) nm, c=0.963 9(3) nm, α=β=γ=90.0°, V=2.089 8(12) nm³, Z=4, D_c=1.416 Mg·m^-3, μ=0.664 mm^-1, F(000)=924, R₁=0.040 2, wR₂=0.133 2 (I>2σ(I))。配合物1的结构单元由1个Mn^Ⅱ、1个1, 3-pda和1个bpp构成。bpp交替连接Mn^Ⅱ形成1D右手螺旋链, 进一步通过1, 3-pda的连接构成2D螺旋层。从c轴方向看, 发现1DZ字链构成2D(4, 4)网格结构。同时还研究了配合物的热稳定性和电化学性质。

关键词:

配合物;合成;晶体结构

English

Synthesis and Crystal Structure of 2D Mn(Ⅱ) Complex with Flexible Phenylenediacetic Ligand

1.
1 College of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan′an University, Yan′an, Shaanxi 716000, China;
Received Date: 07 September 2012
Fund Project:
陕西省教育厅科研基金(No.11JK0567, 11JK0565, 12JK0636)

延安大学自然基金(No.YDZD2011-07)资助项目。

Abstract: A coordination polymer of Mn^Ⅱ with flexible ligands, namely [Mn(pda)(bpp)] (1) (H₂pda=1,3-phenyl-enediacetic acid, bpp=1,3-bi(4-pyridyl)propane), was synthesized and characterized by single-crystal X-ray diffraction, elemental analysis and IR spectroscopy. The results of structure characterization indicate that the complex crystallizes in the orthorhombic space group Pnna with a=1.965 2(6) nm, b=1.103 3(4) nm, c=0.963 9(3) nm, α=β=γ=90.0°, V=2.089 8(12) nm³, Z=4, D_c=1.416 Mg·m^-3, μ=0.664 mm^-1, F(000)=924, and final R₁=0.040 2, wR₂=0.133 2. The crystal structure of complex 1 consists of one Mn^Ⅱ, one 1,3-pda ligand and one bpp ligand. The bpp ligands bridge the Mn^Ⅱ ions to form a one-dimensional(1D) right-handed helical chain along the crystallographic b direction. Moreover, these helical chains are united together through the 1,3-pda ligands to afford a two-dimensional(2D) helical layer. Further investigation of this 2D structure suggests that the Mn^Ⅱ centers are connected to each other by bpp to afford a 1D zigzag chain along the crystallographic c direction. The 1D zigzag chains are interlinked by the 1,3-pda anions, constituting step-shaped 2D (4,4) network. In addition, thermal stability and electrochemistry of 1 have also been studied. CCDC: 885051.

Key words:

complex;synthesis;crystal structure

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

间苯二乙酸构筑的2D锰(Ⅱ)配合物的合成及晶体结构

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Synthesis and Crystal Structure of 2D Mn(Ⅱ) Complex with Flexible Phenylenediacetic Ligand

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间苯二乙酸构筑的2D锰(Ⅱ)配合物的合成及晶体结构

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Synthesis and Crystal Structure of 2D Mn(Ⅱ) Complex with Flexible Phenylenediacetic Ligand

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