红色铱配合物磷光材料及器件的研究进展

赵学森 崔荣朕 李云辉 高莹 崔成哲

引用本文: 赵学森, 崔荣朕, 李云辉, 高莹, 崔成哲. 红色铱配合物磷光材料及器件的研究进展[J]. 应用化学, 2016, 33(9): 1002-1008. doi: 10.11944/j.issn.1000-0518.2016.09.150461 shu
Citation:  ZHAO Xuesen, CUI Rongzhen, LI Yunhui, GOA Ying, CUI Chengzhe. Research Progress on Red Iridium Complexes Phosphorescent Materials and Devices[J]. Chinese Journal of Applied Chemistry, 2016, 33(9): 1002-1008. doi: 10.11944/j.issn.1000-0518.2016.09.150461 shu

红色铱配合物磷光材料及器件的研究进展

    通讯作者: 高莹,副教授;Tel:0431-85582361;Fax:0431-85583008;E-mail:Gaoying5@sina.com;研究方向:无机光电功能材料;崔成哲,工程师;Tel:0433-2853119;Fax:0433-2915915;E-mail:ccz0917@163.com;研究方向:有机植物体香料; 高莹,副教授;Tel:0431-85582361;Fax:0431-85583008;E-mail:Gaoying5@sina.com;研究方向:无机光电功能材料;崔成哲,工程师;Tel:0433-2853119;Fax:0433-2915915;E-mail:ccz0917@163.com;研究方向:有机植物体香料
  • 基金项目:

    吉林省发改委项目(2014Y115,2015Y058)资助 

摘要: 有机电致发光器件具有驱动电压低、高亮度、高效率等优点,引起了研究人员的广泛关注,在固态照明和平板显示领域具有广阔应用前景。在绿、蓝、红三基色器件中,绿光器件和蓝光器件的性能普遍优于红光器件,基本满足了产业化的需要;目前红色有机电致发光材料及器件的研究进展相对缓慢。因为红光材料的能隙较窄,致使主客体材料之间能级匹配困难,导致红光器件普遍效率低、色纯度差,但是,红光材料是获得白光器件必不可少的材料。因此,如何获得高性能红光材料对于有机电致发光器件的发展至关重要。本文综述了近年来红色铱配合物磷光材料及器件的研究进展,对提升效率和色纯度的方法进行重点阐述;并结合现有工作,对红色有机电致磷光材料与器件的前景进行展望。

English

  • 
    1. [1] Pope M,Kallmann H P,Magnante P,et al.Electroluminescence in Organic Crystals[J].J Chem Phys,1963,38(8):2042-2044.[1] Pope M,Kallmann H P,Magnante P,et al.Electroluminescence in Organic Crystals[J].J Chem Phys,1963,38(8):2042-2044.

    2. [2] Vincett P S,Barlow W A,Hann R A,et al.Electrical Conduction and Low Voltage Blue Electroluminescence in Vacuum-Deposited Organic Films[J].Thin Solid Films,1982,94(2):171-183.[2] Vincett P S,Barlow W A,Hann R A,et al.Electrical Conduction and Low Voltage Blue Electroluminescence in Vacuum-Deposited Organic Films[J].Thin Solid Films,1982,94(2):171-183.

    3. [3] Tang C W,Vanslyke S A.Organic Electroluminescent Diodes[J].Appl Phys Lett,1987,51(12):913-915.[3] Tang C W,Vanslyke S A.Organic Electroluminescent Diodes[J].Appl Phys Lett,1987,51(12):913-915.

    4. [4] Burroughes J H,Bradeley D D C,Brown A R,et al.Light-Emitting Diodes Based on Conjugated Polymers[J].Nature,1990,347:539-541.[4] Burroughes J H,Bradeley D D C,Brown A R,et al.Light-Emitting Diodes Based on Conjugated Polymers[J].Nature,1990,347:539-541.

    5. [5] Gustafsson G,Cao Y,Heeger A J,et al.Flexible Light-emitting Diodes Made from Soluble Conducting Polymers[J].Nature,1992,357:477-479.[5] Gustafsson G,Cao Y,Heeger A J,et al.Flexible Light-emitting Diodes Made from Soluble Conducting Polymers[J].Nature,1992,357:477-479.

    6. [6] Cao Y,Treacy G M,Heeger A J,et al.Solution-cast Films of Polyaniline:Optical-quality Transparent Electrodes[J].Appl Phys Lett,1992,60(22):2711-2713.[6] Cao Y,Treacy G M,Heeger A J,et al.Solution-cast Films of Polyaniline:Optical-quality Transparent Electrodes[J].Appl Phys Lett,1992,60(22):2711-2713.

    7. [7] Ma Y G,Zhang H Y,Che C M,et al.Electroluminescence from Triplet Metal-Ligand Charge-Transfer Excited State of Transition Metal Complexes[J].Synth Met,1998,94(3):245-248.[7] Ma Y G,Zhang H Y,Che C M,et al.Electroluminescence from Triplet Metal-Ligand Charge-Transfer Excited State of Transition Metal Complexes[J].Synth Met,1998,94(3):245-248.

    8. [8] Adachi C,Baldo M A,Forrest S R,et al.Nearly 100% Internal Phosphorescence Efficiency in an Organic Light Emitting Device[J].J Appl Phys,2001,90(10):5048-5051.[8] Adachi C,Baldo M A,Forrest S R,et al.Nearly 100% Internal Phosphorescence Efficiency in an Organic Light Emitting Device[J].J Appl Phys,2001,90(10):5048-5051.

    9. [9] Chen D C,Su S J,Cao Y.Nitrogen Heterocycle-Containing Materials for Highly Efficient Phosphorescent OLEDs with Low Operating Voltage[J].J Mater Chem C,2014,2(45):9565-9578.[9] Chen D C,Su S J,Cao Y.Nitrogen Heterocycle-Containing Materials for Highly Efficient Phosphorescent OLEDs with Low Operating Voltage[J].J Mater Chem C,2014,2(45):9565-9578.

    10. [10] Baldo M A,O'Brien D F,You Y,et al.Highly Efficient Phosphorescent Emission from Organic Electroluminescent Devices[J].Nature,1998,395:151-154.[10] Baldo M A,O'Brien D F,You Y,et al.Highly Efficient Phosphorescent Emission from Organic Electroluminescent Devices[J].Nature,1998,395:151-154.

    11. [11] Tsuboyama A,Iwawaki H,Furugori M,et al.Homoleptic Cyclometalated Iridium Complexes with Highly Efficient Red Phosphorescence and Application to Organic Light-Emitting Diode[J].J Am Chem Soc,2003,125(42):12971-12979.[11] Tsuboyama A,Iwawaki H,Furugori M,et al.Homoleptic Cyclometalated Iridium Complexes with Highly Efficient Red Phosphorescence and Application to Organic Light-Emitting Diode[J].J Am Chem Soc,2003,125(42):12971-12979.

    12. [12] Su Y J,Huang H L,Li C L,et al.Highly Efficient Red Electrophosphorescent Devices Based on Iridium Isoquinoline Complexes:Remarkable External Quantum Efficiency over a Wide Range of Current[J].Adv Mater,2003,15(11):884-888.[12] Su Y J,Huang H L,Li C L,et al.Highly Efficient Red Electrophosphorescent Devices Based on Iridium Isoquinoline Complexes:Remarkable External Quantum Efficiency over a Wide Range of Current[J].Adv Mater,2003,15(11):884-888.

    13. [13] Liang B,Jiang C Y,Chen Z,et al.New Iridium Complex as High-Efficiency Red Phosphorescent Emitter in Polymer Light-Emitting Devices[J].J Mater Chem,2006,16(13):1281-1286.[13] Liang B,Jiang C Y,Chen Z,et al.New Iridium Complex as High-Efficiency Red Phosphorescent Emitter in Polymer Light-Emitting Devices[J].J Mater Chem,2006,16(13):1281-1286.

    14. [14] Lu K Y,Chou H H,Hsieh C H.Wide-Range Color Tuning of Iridium Biscarbene Complexes from Blue to Red by Different N^N Ligands:An Alternative Route for Adjusting the Emission Colors[J].Adv Mater,2011,23(42):4933-4937.[14] Lu K Y,Chou H H,Hsieh C H.Wide-Range Color Tuning of Iridium Biscarbene Complexes from Blue to Red by Different N^N Ligands:An Alternative Route for Adjusting the Emission Colors[J].Adv Mater,2011,23(42):4933-4937.

    15. [15] REN Jingkun,XU Huixia,QU Litao,et al.Synthesis and Optoelectronic Properties of a Red-Emitting Iridium (Ⅲ) Complex Containing 1-Phenylpyrazole[J].Acta Phys Chim Sin,2013,29(5):1115-1122(in Chinese).任静琨,许慧侠,屈丽桃,等.以1-苯基吡唑为主配体的红光Ir (Ⅲ)配合物的合成及光电特性[J].物理化学学报,2013,29(05):1115-1122.[15] REN Jingkun,XU Huixia,QU Litao,et al.Synthesis and Optoelectronic Properties of a Red-Emitting Iridium (Ⅲ) Complex Containing 1-Phenylpyrazole[J].Acta Phys Chim Sin,2013,29(5):1115-1122(in Chinese).任静琨,许慧侠,屈丽桃,等.以1-苯基吡唑为主配体的红光Ir (Ⅲ)配合物的合成及光电特性[J].物理化学学报,2013,29(05):1115-1122.

    16. [16] Zhu M R,Li Y H,Jiang B,et al.Efficient Saturated Red Electrophosphorescence by Using Solution-Processed 1-Phenylisoquinoline-Based Iridium Phosphors with Peripheral Functional Encapsulation[J].Org Electron,2015,26:400-407.[16] Zhu M R,Li Y H,Jiang B,et al.Efficient Saturated Red Electrophosphorescence by Using Solution-Processed 1-Phenylisoquinoline-Based Iridium Phosphors with Peripheral Functional Encapsulation[J].Org Electron,2015,26:400-407.

    17. [17] Zhu M R,Li Y H,Miao J S,et al.Multifunctional Homoleptic Iridium (Ⅲ) Dendrimers Towards Solution-Processed Nondoped Electrophosphorescence with Low Efficiency Roll-Off[J].Org Electron,2014,15(7):1598-1606.[17] Zhu M R,Li Y H,Miao J S,et al.Multifunctional Homoleptic Iridium (Ⅲ) Dendrimers Towards Solution-Processed Nondoped Electrophosphorescence with Low Efficiency Roll-Off[J].Org Electron,2014,15(7):1598-1606.

    18. [18] Deng L J,Zhang T,Wang R J,et al.Diphenylphosphorylpyridine-Functionalized Iridium Complexes for High-Efficiency Monochromic and White Organic Light-Emitting Diodes[J].J Mater Chem,2012,22(31):15910-15918.[18] Deng L J,Zhang T,Wang R J,et al.Diphenylphosphorylpyridine-Functionalized Iridium Complexes for High-Efficiency Monochromic and White Organic Light-Emitting Diodes[J].J Mater Chem,2012,22(31):15910-15918.

    19. [19] Lee S J,Lee J S,Hwang K J,et al.Synthesis and Characterization of Phosphoescent Iridium Complexes of 6-Chloro-3-Phenylpyridazine and 3-Chloro-6-(3'-Methoxy-Phenyl)-4-Methyl-Pyridazine[J].Curr Appl Phys,2005,5(1):43-46.[19] Lee S J,Lee J S,Hwang K J,et al.Synthesis and Characterization of Phosphoescent Iridium Complexes of 6-Chloro-3-Phenylpyridazine and 3-Chloro-6-(3'-Methoxy-Phenyl)-4-Methyl-Pyridazine[J].Curr Appl Phys,2005,5(1):43-46.

    20. [20] Tong B H,Mei Q B,Wang S J,et al.Nearly 100% Internal Phosphorescence Efficiency in a Polymer Light-Emitting Diode Using a New Iridium Complex Phosphor[J].J Mater Chem,2008,18(14):1636-1639.[20] Tong B H,Mei Q B,Wang S J,et al.Nearly 100% Internal Phosphorescence Efficiency in a Polymer Light-Emitting Diode Using a New Iridium Complex Phosphor[J].J Mater Chem,2008,18(14):1636-1639.

    21. [21] Guo L Y,Zhang X L,Wang H S,et al.New Homoleptic Iridium Complexes with C^N=N Type Ligand for High Efficiency Orange and Single Emissive-Layer White OLEDs[J].J Mater Chem C,2015,3(21):5412-5418.[21] Guo L Y,Zhang X L,Wang H S,et al.New Homoleptic Iridium Complexes with C^N=N Type Ligand for High Efficiency Orange and Single Emissive-Layer White OLEDs[J].J Mater Chem C,2015,3(21):5412-5418.

    22. [22] Li G M,Zhu D X,Liu Y,et al.Very High Efficiency Orange-Red Light-Emitting Devices with Low Roll-Off at High Luminance Based on an Idea Host-Guest System Consisting of Two Novel Phosphorescent Iridium Complexes with Bipolar Transport[J].Adv Funct Mater,2014,24(47):7420-7426.[22] Li G M,Zhu D X,Liu Y,et al.Very High Efficiency Orange-Red Light-Emitting Devices with Low Roll-Off at High Luminance Based on an Idea Host-Guest System Consisting of Two Novel Phosphorescent Iridium Complexes with Bipolar Transport[J].Adv Funct Mater,2014,24(47):7420-7426.

    23. [23] Li G M,Feng Y S,Peng T,et al.Highly Efficient,Little Efficiency Roll-Off Orange-Red Electrophosphorescent Devices Based on a Bipolar Iridium Complex[J].J Mater Chem C,2015,3(7):1452-1456.[23] Li G M,Feng Y S,Peng T,et al.Highly Efficient,Little Efficiency Roll-Off Orange-Red Electrophosphorescent Devices Based on a Bipolar Iridium Complex[J].J Mater Chem C,2015,3(7):1452-1456.

    24. [24] Zhou L,Kwong C L,Kwok C C,et al.Efficient Red Electroluminescent Devices with Sterically Hindered Phosphorescent Platinum (Ⅱ) Schiff Base Complexes and Iridium Complex Codopant[J].Chem Asian J,2014,9(10):2984-2994.[24] Zhou L,Kwong C L,Kwok C C,et al.Efficient Red Electroluminescent Devices with Sterically Hindered Phosphorescent Platinum (Ⅱ) Schiff Base Complexes and Iridium Complex Codopant[J].Chem Asian J,2014,9(10):2984-2994.

    25. [25] Zhou L,Li L J,Jiang Y L,et al.Rare Earth Complex as Electron Trapper and Energy Transfer Ladder for Efficient Red Iridium Complex Based Electroluminescent Devices[J].Appl Mater Interfaces,2015,7(29):16046-16053.[25] Zhou L,Li L J,Jiang Y L,et al.Rare Earth Complex as Electron Trapper and Energy Transfer Ladder for Efficient Red Iridium Complex Based Electroluminescent Devices[J].Appl Mater Interfaces,2015,7(29):16046-16053.

    26. [26] Lamansky S,Djurovich P,Murphy D,et al.Highly Phosphorescent Bis-Cyclometalated Iridium Complexes:Synthesis,Photophysical Characterization,and Use in Organic Light Emitting Diodes[J].J Am Chem Soc,2001,123(18):4304-4312.[26] Lamansky S,Djurovich P,Murphy D,et al.Highly Phosphorescent Bis-Cyclometalated Iridium Complexes:Synthesis,Photophysical Characterization,and Use in Organic Light Emitting Diodes[J].J Am Chem Soc,2001,123(18):4304-4312.

    27. [27] Xu M L,Wang G Y,Zhou R,et al.Tuning Iridium (Ⅲ) Complexes Containing 2-Benzo[b]thiophen-2-yl-Pyridine Based Ligands in the Red Region[J].Inorg Chim Acta,2007,360(10):3149-3154.[27] Xu M L,Wang G Y,Zhou R,et al.Tuning Iridium (Ⅲ) Complexes Containing 2-Benzo[b]thiophen-2-yl-Pyridine Based Ligands in the Red Region[J].Inorg Chim Acta,2007,360(10):3149-3154.

    28. [28] Zhou G J,Wong W Y,Yao B,et al.Triphenylamine-Dendronized Pure Red Iridium Phosphors with Superior OLED Efficiency/Color Purity Trade-Offs[J].Angew Chem Int Ed,2007,46(7):1149-1151.[28] Zhou G J,Wong W Y,Yao B,et al.Triphenylamine-Dendronized Pure Red Iridium Phosphors with Superior OLED Efficiency/Color Purity Trade-Offs[J].Angew Chem Int Ed,2007,46(7):1149-1151.

    29. [29] Li Y,Zhang W,Zhang L T,et al.Ultra-High General and Special Color Rendering Index White Organic Light-Emitting Device Based on a Deep Red Phosphorescent Dye[J].Org Electron,2013,14(12):3201-3205.[29] Li Y,Zhang W,Zhang L T,et al.Ultra-High General and Special Color Rendering Index White Organic Light-Emitting Device Based on a Deep Red Phosphorescent Dye[J].Org Electron,2013,14(12):3201-3205.

    30. [30] Baranoff E,Yum J H,Graetzel M,et al.Cyclometallated Iridium Complexes for Conversion of Light into Electricity and Electricity into Light[J].J Organoment Chem,2009,694(17):2661-2670.[30] Baranoff E,Yum J H,Graetzel M,et al.Cyclometallated Iridium Complexes for Conversion of Light into Electricity and Electricity into Light[J].J Organoment Chem,2009,694(17):2661-2670.

    31. [31] Li J Y,Wang R J,Yang R X,et al.Iridium Complexes Containing 2-Aryl-benzothiazole Ligands:Color Tuning and Application in High-Performance Organic Light-Emitting Diodes[J].J Mater Chem C,2013,1(26):4171-4179.[31] Li J Y,Wang R J,Yang R X,et al.Iridium Complexes Containing 2-Aryl-benzothiazole Ligands:Color Tuning and Application in High-Performance Organic Light-Emitting Diodes[J].J Mater Chem C,2013,1(26):4171-4179.

    32. [32] Kim H U,Jang J H,Song W,et al.Improved Luminance and External Quantum Efficiency of Red and White Organic Light-Emitting Diodes with Iridium (Ⅲ) Complexes with Phenyl-Substituted 2-Phenylpyridine as a Second Cyclometalated Ligand[J].J Mater Chem C,2015,3(46):12107-12115.[32] Kim H U,Jang J H,Song W,et al.Improved Luminance and External Quantum Efficiency of Red and White Organic Light-Emitting Diodes with Iridium (Ⅲ) Complexes with Phenyl-Substituted 2-Phenylpyridine as a Second Cyclometalated Ligand[J].J Mater Chem C,2015,3(46):12107-12115.

  • 加载中
计量
  • PDF下载量:  1
  • 文章访问数:  691
  • HTML全文浏览量:  84
文章相关
  • 收稿日期:  2015-12-28
  • 网络出版日期:  2016-04-15
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章