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两个含有混磷配体的发光银(Ⅰ)配合物的合成和表征

张彦茹 ,  王梦秦 ,  崔洋哲 ,  刘敏 ,  李中峰 ,  金琼花

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引用本文: 张彦茹, 王梦秦, 崔洋哲, 刘敏, 李中峰, 金琼花. 两个含有混磷配体的发光银(Ⅰ)配合物的合成和表征[J]. 无机化学学报, 2015, 31(10): 2089-2094. doi: 10.11862/CJIC.2015.274 shu
Citation:  ZHANG Yan-Ru, WANG Meng-Qin, CUI Yang-Zhe, LIU Min, LI Zhong-Feng, JIN Qiong-Hua. Syntheses and Characterization of Two Luminescent Silver(Ⅰ) Complexes Based on Mixed Phosphine Ligands[J]. Chinese Journal of Inorganic Chemistry, 2015, 31(10): 2089-2094. doi: 10.11862/CJIC.2015.274 shu

两个含有混磷配体的发光银(Ⅰ)配合物的合成和表征

  • 1.

    1 首都师范大学化学系, 北京 100048;

  • 2.

    2 北京工业大学材料科学与工程学院, 北京 100124

    • 通讯作者: 金琼花,E-mail:jinqh@cnu.edu.cn
  • 基金项目:

    国家自然科学基金(No.21171119) (No.21171119)

    863国家高技术研究发展计划(No.2012AA063201) (No.2012AA063201)

    北京教育委员会基金(No.KM201210028020) (No.KM201210028020)

    北京市优秀人才项目(No.2010D005016000002) (No.2010D005016000002)

    北京市自然科学基金(No.7122015)资助项目。 (No.7122015)

摘要: 合成了两个新的银(Ⅰ)配合物,[Ag2Br2(DPEphos)2(dppe)](1)和[Ag(DPEphos)(dppe)]NO3(2)(DPEphos=双[(2-二苯膦基)苯基]醚;dppe=1,2-双(二苯膦)乙烷),通过红外光谱、X-射线单晶衍射、核磁共振氢谱、磷谱和荧光光谱进行分析和表征。1是由AgBr, DPEphos和dppe以2:2:1的比例混合反应得到的双核化合物,dppe通过2个P原子桥连2个Ag原子,而2是由AgNO3,DPEphos和dppe以1:1:1的比例混合反应得到的简单的单核化合物,Ag原子与DPEphos和dppe配体螯合。在配合物2的膦谱中,存在4个分裂峰(双峰或者三重峰)。荧光光谱表明所有的发射峰均源于配体中的π-π*跃迁。

English

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  • 收稿日期:  2015-06-28
  • 网络出版日期:  2015-07-12
通讯作者: 陈斌, bchen63@163.com
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