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基于双(1,2,4-三氮唑基)刚性配体和芳香羧酸的两个配位聚合物的合成、晶体结构及荧光性质

王哓哓 ,  刘永光 ,  葛明 ,  崔广华

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引用本文: 王哓哓, 刘永光, 葛明, 崔广华. 基于双(1,2,4-三氮唑基)刚性配体和芳香羧酸的两个配位聚合物的合成、晶体结构及荧光性质[J]. 无机化学学报, 2015, 31(10): 2065-2072. doi: 10.11862/CJIC.2015.273 shu
Citation:  WANG Xiao-Xiao, LIU Yong-Guang, GE Ming, CUI Guang-Hua. Syntheses, Crystal Structures and Fluorescence Properties of Two Metal-Organic Coordination Polymers Derived from Rigid Bis(1,2,4-triazolyl) and Aromatic Carboxylic Acid Ligands[J]. Chinese Journal of Inorganic Chemistry, 2015, 31(10): 2065-2072. doi: 10.11862/CJIC.2015.273 shu

基于双(1,2,4-三氮唑基)刚性配体和芳香羧酸的两个配位聚合物的合成、晶体结构及荧光性质

  • 1.

    华北理工大学化学工程学院, 唐山 063009

    • 通讯作者: 崔广华,E-mail:tscghua@126.com
  • 基金项目:

    国家自然科学基金(No.51474086) (No.51474086)

    河北省自然科学基金-钢铁联合研究基金(No.B2015209299)资助项目。 (No.B2015209299)

摘要: 水热条件下,合成了2个结构新颖的金属配位聚合物:[Co1.5(btb)2(nbta)(H2O)2]n(1),[Cd(btb)0.5(nph)(H2O)]n(2)(btb=4,4'-二(1,2,4-三氮唑-1-基)联苯,H3nbta=5-硝基-1,2,3-苯三甲酸,H2nph=3-硝基邻苯二甲酸)并对它们进行了元素分析,红外光谱及X-射线单晶衍射等表征。结构分析表明,化合物1是一个二维(3,4)-连接3,4L90拓扑结构,并进一步通过O-H…O氢键作用构筑成三维超分子结构。而配合物2是一个三维(3,4,4)-连接的sqc69网络,它的拓扑符号为(4.82)2(42.82.102)(8.104.12)。此外,还研究了这两个配合物的热重和荧光性质。

English

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  • 收稿日期:  2015-03-23
  • 网络出版日期:  2015-07-13
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