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二维大环网状结构的双(三环已基锡)二元酸酯的合成、结构及生物活性

邝代治 ,  朱小明 ,  冯泳兰 ,  张复兴 ,  庾江喜 ,  蒋伍玖 ,  谭宇星 ,  张志坚

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引用本文: 邝代治, 朱小明, 冯泳兰, 张复兴, 庾江喜, 蒋伍玖, 谭宇星, 张志坚. 二维大环网状结构的双(三环已基锡)二元酸酯的合成、结构及生物活性[J]. 无机化学学报, 2015, 31(10): 2044-2050. doi: 10.11862/CJIC.2015.268 shu
Citation:  KUANG Dai-Zhi, ZHU Xiao-Ming, FENG Yong-Lan, ZHANG Fu-Xing, YU Jiang-Xi, JIANG Wu-Jiu, TAN Yu-Xing, ZHANG Zhi-Jian. Syntheses, Crystal Structures and Biological Activities of Bis(tricyclohexyltin)dicarboxylates with Macrocyclic Building 2D Network[J]. Chinese Journal of Inorganic Chemistry, 2015, 31(10): 2044-2050. doi: 10.11862/CJIC.2015.268 shu

二维大环网状结构的双(三环已基锡)二元酸酯的合成、结构及生物活性

  • 1.

    1 衡阳师范学院化学与材料科学学院, 功能金属有机材料湖南省普通高等学校重点实验室, 衡阳 421008;

  • 2.

    2 衡阳师范学院生命科学与环境学院, 衡阳 421008

    • 通讯作者: 邝代治,E-mail:hnkcq@qq.com
  • 基金项目:

    湖南省自然科学基金(13JJ3112) (13JJ3112)

    科技计划(2014NK3086,2014FJ3060)项目,功能金属有机材料湖南省普通高校重点实验室开放基金资助项目(13K105,14K014,13K01-05,GN14K01) (2014NK3086,2014FJ3060)项目,功能金属有机材料湖南省普通高校重点实验室开放基金资助项目(13K105,14K014,13K01-05,GN14K01)

    湖南省重点学科基金和湖南省高校科技创新团队支持计划资助项目,衡阳师范学院协同创新中心培育项目(No.12XT02) (No.12XT02)

    湖南省教育厅基金项目(No.15C0199,15C0200,14C0171,14C0168)资助。 (No.15C0199,15C0200,14C0171,14C0168)

摘要: 三环己基氢氧化锡分别与辛二酸和壬二酸进行甲醇溶剂热反应,合成了2个双(三环已基锡)二元酸酯(CH2)n(CO2SnCy3)2[(n:6(1),7(2)],并用IR、1H和13C NMR、元素分析和X射线单晶衍射表征结构。化合物1、2均属单斜晶系,空间群分别为P21/n和P21/c,在化合物的晶体中,1通过Sn-O共价键,2通过Sn-O和Sn…O弱作用,分别形成了四锡核30元(1)和32元(2)二维大环网状结构。化合物1、2对人癌细胞Colo205、HepG2、MCF-7、Hela、NCI-H460均具有良好的体外抑制活性,对S. Aureus、B. Subtilis、E. Coli和S. Typhi具有选择性的抑菌作用。

English

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  • 收稿日期:  2015-05-26
  • 网络出版日期:  2015-07-15
通讯作者: 陈斌, bchen63@163.com
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