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纳米、微米一水草酸钙和二水草酸钙对非离子表面活性剂NP-40的吸附差异

温小玲 ,  甘琼枝 ,  欧阳健明

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引用本文: 温小玲, 甘琼枝, 欧阳健明. 纳米、微米一水草酸钙和二水草酸钙对非离子表面活性剂NP-40的吸附差异[J]. 无机化学学报, 2015, 31(10): 2021-2029. doi: 10.11862/CJIC.2015.266 shu
Citation:  WEN Xiao-Ling, GAN Qiong-Zhi, OUYANG Jian-Ming. Adsorption of Nonionic Surfactant NP-40 on Micron/Nano Calcium Oxalate Monohydrate and Dihydrate Crystals[J]. Chinese Journal of Inorganic Chemistry, 2015, 31(10): 2021-2029. doi: 10.11862/CJIC.2015.266 shu

纳米、微米一水草酸钙和二水草酸钙对非离子表面活性剂NP-40的吸附差异

  • 1.

    暨南大学生物矿化与结石病防治研究所, 暨南大学化学系, 广州 510632

    • 通讯作者: 欧阳健明,E-mail:toyjm@jnu.edu.cn
  • 基金项目:

    国家自然科学基金(No.21371077)资助项目。 (No.21371077)

摘要: 为探究CaOx结石的形成机理,测定了不同浓度NP-40(cNP-40)存在下各尺寸COM或COD晶体的吸附量;采用X射线衍射和红外光谱研究吸附前后晶体是否发生晶相改变;采用ζ电位仪测定吸附后晶体表面的ζ电位随cNP-40的变化。结果表明:不同尺寸COM、COD对NP-40的吸附能力大小顺序为:50 nm > 100 nm > 1μm > > 3μm > 10μm;相同尺寸的晶体,COM的吸附量大于COD。随着cNP-40增加,3μm和10μm的COM、COD晶体的吸附曲线为S型,而50 nm、100 nm、1μm的COM、COD晶体的吸附曲线为直线型。加入NP-40后,ζ电位绝对值与各晶体的吸附密度成正相关。提出了草酸钙晶体吸附NP-40的分子模型。晶体尺寸越小,对NP-40的吸附量越大。非离子表面活性剂虽然自身不带电荷,但吸附到COM、COD晶体表面后可以通过位阻斥力来增加晶体悬浮液的稳定性,有利于抑制草酸钙结石的形成。

English

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    1. [1] Zhao Z, Xia Y, Xue J, et al. Cryst. Growth Des., 2013,14(2):450-458[1] Zhao Z, Xia Y, Xue J, et al. Cryst. Growth Des., 2013,14(2):450-458

    2. [2] Prywer J, Sadowski R R, Torzewska A. Cryst. Growth Des., 2015,15:1446-1451[2] Prywer J, Sadowski R R, Torzewska A. Cryst. Growth Des., 2015,15:1446-1451

    3. [3] Hussein N S, Sadiq S M, Kamaliah M D, et al. Saudi J. Kidney Diseases Transplantation, 2013,24(3):630[3] Hussein N S, Sadiq S M, Kamaliah M D, et al. Saudi J. Kidney Diseases Transplantation, 2013,24(3):630

    4. [4] Farmanesh S, Ramamoorthy S, Chung J, et al. J. Am. Chem. Soc., 2014,136(1):367-376[4] Farmanesh S, Ramamoorthy S, Chung J, et al. J. Am. Chem. Soc., 2014,136(1):367-376

    5. [5] Hess B, Kok D J. Kidney Stones:Mesical and Surgical Management. Philadelphia:Lippincott-Raven Publishers, 1996:3-32[5] Hess B, Kok D J. Kidney Stones:Mesical and Surgical Management. Philadelphia:Lippincott-Raven Publishers, 1996:3-32

    6. [6] SikiriM, Filipovi-Vincekovi N, Babi-Ivani V, et al. J. Colloid Interface Sci., 1999,212(2):384-389[6] SikiriM, Filipovi-Vincekovi N, Babi-Ivani V, et al. J. Colloid Interface Sci., 1999,212(2):384-389

    7. [7] Saso L, Grippa E, Gatto M T, et al. Int. J. Urol., 2001,8(3):124-127[7] Saso L, Grippa E, Gatto M T, et al. Int. J. Urol., 2001,8(3):124-127

    8. [8] Zhang D, Qi L, Ma J, Cheng H. Chem. Mater., 2002,14(6):2450-2457[8] Zhang D, Qi L, Ma J, Cheng H. Chem. Mater., 2002,14(6):2450-2457

    9. [9] Wei X, Yang J, Li Z, et al. Collodis Surf. A, 2012,401:107-115[9] Wei X, Yang J, Li Z, et al. Collodis Surf. A, 2012,401:107-115

    10. [10] Sikiri M D, Füredi-Milhofer H. Adv. Colloid Interface Sci., 2006,128:135-158[10] Sikiri M D, Füredi-Milhofer H. Adv. Colloid Interface Sci., 2006,128:135-158

    11. [11] Dong R, Weng R, Dou Y, et al. J. Phys. Chem. B, 2010,114(6):2131-2139[11] Dong R, Weng R, Dou Y, et al. J. Phys. Chem. B, 2010,114(6):2131-2139

    12. [12] Sharma K P, Aswal V K, Kumaraswamy G. J. Phys. Chem. B, 2010,114(34):10986-10994[12] Sharma K P, Aswal V K, Kumaraswamy G. J. Phys. Chem. B, 2010,114(34):10986-10994

    13. [13] Thwala J M, Goodwin J W, Mills P D. Colloids Surf. A, 2008, 331(3):162-174[13] Thwala J M, Goodwin J W, Mills P D. Colloids Surf. A, 2008, 331(3):162-174

    14. [14] Paria S, Yuet P K. Ind. Eng. Chem. Res., 2007,46(1):108-113[14] Paria S, Yuet P K. Ind. Eng. Chem. Res., 2007,46(1):108-113

    15. [15] Berezin M B, Kustov A V, Smirnova N L, et al. Russ. J. Inorg. Chem., 2011,56(1):139-140[15] Berezin M B, Kustov A V, Smirnova N L, et al. Russ. J. Inorg. Chem., 2011,56(1):139-140

    16. [16] Gao J, Xue J F, Xu M, et al. Int. J. Nanomed., 2014,9:4399-4409[16] Gao J, Xue J F, Xu M, et al. Int. J. Nanomed., 2014,9:4399-4409

    17. [17] LIU Yi-Ming(柳一鸣), XIA Zhi-Yue(夏志月), OUYANG Jing-Ming(欧阳健明), et al. Chinese J. Inorg. Chem.(无机化学学报), 2013,29(5):903-909[17] LIU Yi-Ming(柳一鸣), XIA Zhi-Yue(夏志月), OUYANG Jing-Ming(欧阳健明), et al. Chinese J. Inorg. Chem.(无机化学学报), 2013,29(5):903-909

    18. [18] Brown D G, Jaffe P R. Environ. Sci. Technol., 2001,35:2022-2025[18] Brown D G, Jaffe P R. Environ. Sci. Technol., 2001,35:2022-2025

    19. [19] Kulaksizoglu S, Sofikerim M, Cevik C. Int. J. Urol., 2007,14(3):214-218[19] Kulaksizoglu S, Sofikerim M, Cevik C. Int. J. Urol., 2007,14(3):214-218

    20. [20] Christmas K G, Gower L B, Khan S R, et al. J. Colloid Interface Sci., 2002,256(1):168-174[20] Christmas K G, Gower L B, Khan S R, et al. J. Colloid Interface Sci., 2002,256(1):168-174

    21. [21] LI Quan(李泉), ZENG Guang-Fu(曾广赋), XI Shi-Quan (席时权). Chemistry(化学通报), 1995(6):29-34[21] LI Quan(李泉), ZENG Guang-Fu(曾广赋), XI Shi-Quan (席时权). Chemistry(化学通报), 1995(6):29-34

    22. [22] Fuangswasdi A, Charoensaeng A, Sabatini D A, et al. J. Surfactants Deterg., 2006,9(1):21-28[22] Fuangswasdi A, Charoensaeng A, Sabatini D A, et al. J. Surfactants Deterg., 2006,9(1):21-28

    23. [23] Tunik L, Füredi-Milhofer H, Garti N. Langmuir, 1998,14(12):3351-3355[23] Tunik L, Füredi-Milhofer H, Garti N. Langmuir, 1998,14(12):3351-3355

    24. [24] Katepalli H, John V T, Bose A. Langmuir, 2013,29(23):6790-6797[24] Katepalli H, John V T, Bose A. Langmuir, 2013,29(23):6790-6797

    25. [25] Han Z, Zhang F, Lin D, et al. Environ. Sci. Technol., 2008, 42(18):6869-6875[25] Han Z, Zhang F, Lin D, et al. Environ. Sci. Technol., 2008, 42(18):6869-6875

    26. [26] Qiu S R, Wierzbicki A, Salter E A, et al. J. Am. Chem. Soc., 2005,127:9036-9044[26] Qiu S R, Wierzbicki A, Salter E A, et al. J. Am. Chem. Soc., 2005,127:9036-9044

    27. [27] Zhang R, Somasundaran P. Adv. Colloid Interface Sci., 2006, 123:213-229[27] Zhang R, Somasundaran P. Adv. Colloid Interface Sci., 2006, 123:213-229

    28. [28] Shemetov A A, Nabiev I, Sukhanova A. ACS Nano, 2012,6(6):4585-4602[28] Shemetov A A, Nabiev I, Sukhanova A. ACS Nano, 2012,6(6):4585-4602

    29. [29] Farmanesh S, Chung J, Sosa R D. J. Am. Chem. Soc., 2014, 136(36):12648-12657[29] Farmanesh S, Chung J, Sosa R D. J. Am. Chem. Soc., 2014, 136(36):12648-12657

    30. [30] Nevskaia D M, Guerrero-Ru A, López-González J D. J. Colloid Interface Sci., 1998,205(1):97-105[30] Nevskaia D M, Guerrero-Ru A, López-González J D. J. Colloid Interface Sci., 1998,205(1):97-105

    31. [31] King M, Mcclure W F, Andrews L C. International center for diffraction data:Newtown Square, PA, 1992.[31] King M, Mcclure W F, Andrews L C. International center for diffraction data:Newtown Square, PA, 1992.

    32. [32] Cody A M, Cody R D. J. Cryst. Growth, 1994,135(1):235-245[32] Cody A M, Cody R D. J. Cryst. Growth, 1994,135(1):235-245

    33. [33] Yao X Q, Ouyang J M, Peng H, et al. Carbohydr. Polym., 2012,90(7):392-398[33] Yao X Q, Ouyang J M, Peng H, et al. Carbohydr. Polym., 2012,90(7):392-398

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  • 收稿日期:  2015-03-24
  • 网络出版日期:  2015-08-26
通讯作者: 陈斌, bchen63@163.com
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