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两个基于四面体型配体的镉配合物的合成、晶体结构及性质

梁丽丽 ,  徐磊 ,  陈飞剑 ,  司友琳 ,  陶兆林 ,  薛洪宝

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引用本文: 梁丽丽, 徐磊, 陈飞剑, 司友琳, 陶兆林, 薛洪宝. 两个基于四面体型配体的镉配合物的合成、晶体结构及性质[J]. 无机化学学报, 2015, 31(10): 1993-2000. doi: 10.11862/CJIC.2015.210 shu
Citation:  LIANG Li-Li, XU Lei, CHEN Fei-Jian, SI You-Lin, TAO Zhao-Lin, XUE Hong-Bao. Syntheses, Structures and Properties of Two Cadmium Complexes Constructed from a Flexible Tetrahedral Ligand[J]. Chinese Journal of Inorganic Chemistry, 2015, 31(10): 1993-2000. doi: 10.11862/CJIC.2015.210 shu

两个基于四面体型配体的镉配合物的合成、晶体结构及性质

  • 1.

    1 南京大学化学化工学院配位化学国家重点实验室, 南京 210093;

  • 2.

    2 蚌埠医学院化学教研室, 蚌埠 233030

    • 通讯作者: 薛洪宝,E-mail:hongbaoxueqhd@126.com
  • 基金项目:

    安徽省自然科学基金(No.1308085QB24) (No.1308085QB24)

    安徽省优秀青年人才基金重点项目(No.2013SQRL051ZD) (No.2013SQRL051ZD)

    南京大学配位化学国家重点实验室开放课题资助项目。 

摘要: 用四面体构型的配体四[3-(羧基苯)氧甲基]甲烷(H4L)与镉离子通过溶剂热法合成了结构不同的配合物[Cd6L3(DMA)3(H2O)]n(1)和{[Cd2L(H2O)4]·4H2O}n(2)(L=四[3-(羧基苯)氧甲基]甲烷)。化合物1属于三方晶系R3空间群。每个配体通过4个羧基连接了4个三核镉簇,每个三核镉簇连接了6个苯甲酸,形成双节点(4,6)-连接toc拓扑构型的三维骨架结构。配合物2属于单斜晶系C2/c空间群。每个配体连接了4个镉原子,仍保持四面体构型。镉原子由羧基沿着b轴连接成一维链,链与链之间通过配体连接,且2个相邻配体的苯环之间存在π-π堆积。此外,对化合物1和2在室温下做了固态紫外和荧光性质的研究。

English

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    1. [1] Allendorf M D, Bauer C A, Bhakta R K, et al. Chem. Soc. Rev., 2009,38:1330-1352[1] Allendorf M D, Bauer C A, Bhakta R K, et al. Chem. Soc. Rev., 2009,38:1330-1352

    2. [2] Cui Y, Xu H, Yue Y, et al. J. Am. Chem. Soc., 2012,134:3979-3982[2] Cui Y, Xu H, Yue Y, et al. J. Am. Chem. Soc., 2012,134:3979-3982

    3. [3] Barea E, Montoro C, Navarro J A. Chem. Soc. Rev., 2014, 43:5419-5430[3] Barea E, Montoro C, Navarro J A. Chem. Soc. Rev., 2014, 43:5419-5430

    4. [4] He Y B, Zhou W, Qian, G D, et al. Chem. Soc. Rev., 2014, 43:5657-5678[4] He Y B, Zhou W, Qian, G D, et al. Chem. Soc. Rev., 2014, 43:5657-5678

    5. [5] Voorde B V, Bueken B, Denayer J, et al. Chem. Soc. Rev., 2014,43:5766-5788[5] Voorde B V, Bueken B, Denayer J, et al. Chem. Soc. Rev., 2014,43:5766-5788

    6. [6] Chen B, Wang L, Xiao Y, et al. Angew. Chem. Int. Ed., 2009,48:500-503[6] Chen B, Wang L, Xiao Y, et al. Angew. Chem. Int. Ed., 2009,48:500-503

    7. [7] Zhang M, Feng G, Song X, et al. J. Am. Chem. Soc., 2014, 136:7241-7244[7] Zhang M, Feng G, Song X, et al. J. Am. Chem. Soc., 2014, 136:7241-7244

    8. [8] Hu Z C, Deibert B J, Li J. Chem. Soc. Rev., 2014,43:5815-5840[8] Hu Z C, Deibert B J, Li J. Chem. Soc. Rev., 2014,43:5815-5840

    9. [9] Yoon M, Srirambalaji R, Kim K. Chem. Rev., 2012,112:1196-1231[9] Yoon M, Srirambalaji R, Kim K. Chem. Rev., 2012,112:1196-1231

    10. [10] Dhakshinamoorthy A, Garcia H. Chem. Soc. Rev., 2014,43:5750-5765[10] Dhakshinamoorthy A, Garcia H. Chem. Soc. Rev., 2014,43:5750-5765

    11. [11] Liu J, Chen L, Cui H. Chem. Soc. Rev., 2014,43:6011-6061[11] Liu J, Chen L, Cui H. Chem. Soc. Rev., 2014,43:6011-6061

    12. [12] Zhang J P, Zhang Y B, Lin J B, et al. Chem. Rev., 2012, 112:1001-1033[12] Zhang J P, Zhang Y B, Lin J B, et al. Chem. Rev., 2012, 112:1001-1033

    13. [13] Schneemann A, Bon V, Schwedler I, et al. Chem. Soc. Rev., 2014,43:6062-96[13] Schneemann A, Bon V, Schwedler I, et al. Chem. Soc. Rev., 2014,43:6062-96

    14. [14] Liang L L, Zhang J, Ren S B, et al. CrystEngComm, 2010, 12:2008-2010[14] Liang L L, Zhang J, Ren S B, et al. CrystEngComm, 2010, 12:2008-2010

    15. [15] Liang L L, Ren S B, Zhang J, et al. Dalton Trans., 2010,39:7723-7726[15] Liang L L, Ren S B, Zhang J, et al. Dalton Trans., 2010,39:7723-7726

    16. [16] Liang L L, Ren S B, Zhang J, et al. CrystEngComm, 2010, 12:2669-2771[16] Liang L L, Ren S B, Zhang J, et al. CrystEngComm, 2010, 12:2669-2771

    17. [17] Yuan W B, Li H F, Guo Z G, et al. Inorg. Chem. Commun., 2011,14:366-369[17] Yuan W B, Li H F, Guo Z G, et al. Inorg. Chem. Commun., 2011,14:366-369

    18. [18] CAO Cheng(曹成), WEI Tai-Bao(魏太保), ZHANG Qin-Sheng(张勤生), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012,28:2530-2534[18] CAO Cheng(曹成), WEI Tai-Bao(魏太保), ZHANG Qin-Sheng(张勤生), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012,28:2530-2534

    19. [19] Kim H, Suh M P. Inorg. Chem., 2005,44:810-812[19] Kim H, Suh M P. Inorg. Chem., 2005,44:810-812

    20. [20] Software Packages SMART and SAINT, Siemens Analytical X-ray Instrument Inc., Madison:WI, 1996.[20] Software Packages SMART and SAINT, Siemens Analytical X-ray Instrument Inc., Madison:WI, 1996.

    21. [21] Sheldrick G M. SHELXS-97, Program for X-ray Crystal Structure Solution, University of Göttingen, Göttingen, Germany, 1997.[21] Sheldrick G M. SHELXS-97, Program for X-ray Crystal Structure Solution, University of Göttingen, Göttingen, Germany, 1997.

    22. [22] Dolomanov O, Puschmann H. OLEX2, 2009.[22] Dolomanov O, Puschmann H. OLEX2, 2009.

    23. [23] Sheldrick G M. SHELXL-97, Program for X-ray Crystal Structure Refinement, University of Göttingen, Göttingen, Germany, 1997.[23] Sheldrick G M. SHELXL-97, Program for X-ray Crystal Structure Refinement, University of Göttingen, Göttingen, Germany, 1997.

    24. [24] Spek A L. J. Appl. Crystallogr., 2003,36:7-13[24] Spek A L. J. Appl. Crystallogr., 2003,36:7-13

    25. [25] Janiak C. J. Chem. Soc., Dalton Trans., 2000:3885-3896[25] Janiak C. J. Chem. Soc., Dalton Trans., 2000:3885-3896

    26. [26] Cui Y, Yue Y, Chen B, et al. Chem. Rev., 2012,112:1126-1162[26] Cui Y, Yue Y, Chen B, et al. Chem. Rev., 2012,112:1126-1162

    27. [27] Yam V V W, Lo K K W. Chem. Soc. Rev., 1999,28:323-334[27] Yam V V W, Lo K K W. Chem. Soc. Rev., 1999,28:323-334

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  • 收稿日期:  2015-03-16
  • 网络出版日期:  2015-06-16
通讯作者: 陈斌, bchen63@163.com
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