KBi<sub>4</sub>F<sub>13</sub>:一个具有高激光损伤阈值的中红外非线性光学材料

引用本文: 吴奇, 刘宏鸣, 姜方超, 孟祥高, 陈兴国, 杨蕾, 胡章贵, 秦金贵. KBi₄F₁₃:一个具有高激光损伤阈值的中红外非线性光学材料[J]. 无机化学学报, 2015, 31(9): 1875-1880. doi: 10.11862/CJIC.2015.238 shu

Citation: WU Qi, LIU Hong-Ming, JINANG Fang-Chao, MENG Xiang-Gao, CHEN Xing-Guo, YANG Lei, HU Zhang-Gui, QIN Jin-Gui. KBi₄F₁₃: An Infrared Nonlinear Optical Material with High Laser Damage Threshold[J]. Chinese Journal of Inorganic Chemistry, 2015, 31(9): 1875-1880. doi: 10.11862/CJIC.2015.238 shu

KBi₄F₁₃:一个具有高激光损伤阈值的中红外非线性光学材料

吴奇 ^1, ,
刘宏鸣 ^1, ,
姜方超 ^1, ,
孟祥高 ^2, ,
陈兴国 ^1, ,
杨蕾 ^3, ,
胡章贵 ^3, ,
秦金贵 ^{1,
,}

1.
1. 武汉大学化学与分子科学学院, 武汉 430072;
2.
2. 华中师范大学化学学院, 武汉 430079;
3.
3. 中国科学院理化技术研究所, 北京 100190

通讯作者: 秦金贵,E-mail:jgqin@whu.edu.cn

基金项目:
国家自然科学基金重大研究计划重点支持项目(No.91022036) (No.91022036)

国家重点基础研究计划(973计划)(No.2010CB630701)资助项目。 (973计划)(No.2010CB630701)

摘要: 通过KF和Bi₂O₃在HF的水溶液中的水热反应合成了化合物KBi₄F₁₃,首次用X-射线单晶衍射技术鉴定了它的晶体结构。对它进行了XRD、ATR-FTIR、UV-Vis-NIR、TG、SHG测试。测试结果表明该化合物具有能够相位匹配的二阶非线性光学性能,其粉末倍频效应强度约为KDP的一半;粉末激光损伤阈值为120 MW·cm^-2,远远高于同等条件下测试的商品化红外非线性光学材料AgGaS₂的粉末激光损伤阈值(5 MW·cm^-2);粉末的红外吸收边可达20 μm;热分解温度为220℃。以上结果表明该物是有潜在应用价值的具有高激光损伤阈值的中红外非线性光学晶体材料。

关键词:

含Bi卤化物;单晶结构;非线性光学材料;激光损伤阈值;中红外波段

English

KBi₄F₁₃: An Infrared Nonlinear Optical Material with High Laser Damage Threshold

1.
1. Department of Chemistry, Wuhan University, Wuhan 430072, China;
2.
2. College of Chemistry, Central China Normal University, Wuhan 430079, China;
3.
3. Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China

Corresponding author: 秦金贵,E-mail:jgqin@whu.edu.cn

Received Date: 01 June 2015
Fund Project:
国家自然科学基金重大研究计划重点支持项目(No.91022036)

国家重点基础研究计划(973计划)(No.2010CB630701)资助项目。

Abstract: KBi₄F₁₃ was synthesized by hydrothermal reaction of KF and Bi₂O₃ in aqueous solution of HF. Its crystal structure was determined by X-ray diffraction on the single crystal for the first time. Its potential as a new mid-IR nonlinear optical (NLO) material has been investigated. Its powders exhibit a phase-matchable second harmonic generation (SHG) effect as strong as a half of KDP. The laser damage threshold (LDT) value of its powders is measured to be 120 MW·cm^-2, which is much higher than that of the currently commercialized IR NLO material AgGaS₂ (5 MW·cm^-2, measured in the same condition). Its powders show the transparent window in infrared region up to 20 μm, and it is thermally stable up to 220℃. These results indicate that KBi₄F₁₃ is a potentially useful new mid-IR NLO material with a high LDT.

Key words:

bismuth halide;single crystal structure;nonlinear optical material;laser damage threshold;mid-infrared region

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沈阳化工大学材料科学与工程学院沈阳 110142

KBi₄F₁₃:一个具有高激光损伤阈值的中红外非线性光学材料

通讯作者: 秦金贵,E-mail:jgqin@whu.edu.cn

English

KBi₄F₁₃: An Infrared Nonlinear Optical Material with High Laser Damage Threshold

Corresponding author: 秦金贵,E-mail:jgqin@whu.edu.cn

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通讯作者: 秦金贵,E-mail:jgqin@whu.edu.cn

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KBi4F13: An Infrared Nonlinear Optical Material with High Laser Damage Threshold

Corresponding author: 秦金贵,E-mail:jgqin@whu.edu.cn

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