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异金属簇{LnCu3}低温磁制冷性能

李焓 ,  宋芬 ,  师唯 ,  马建功 ,  程鹏

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引用本文: 李焓, 宋芬, 师唯, 马建功, 程鹏. 异金属簇{LnCu3}低温磁制冷性能[J]. 无机化学学报, 2015, 31(9): 1860-1866. doi: 10.11862/CJIC.2015.248 shu
Citation:  LI Han SONG, Fen SHI, Wei MA, CHENG Peng. Cryogenic Magnetic Refrigeration Properties of Heterometallic {LnCu3} Cluster Family[J]. Chinese Journal of Inorganic Chemistry, 2015, 31(9): 1860-1866. doi: 10.11862/CJIC.2015.248 shu

异金属簇{LnCu3}低温磁制冷性能

  • 1.

    南开大学化学学院, 先进能源材料化学教育部重点实验室, 天津化学化工协同创新中心, 天津 300071

    • 通讯作者: 程鹏,E-mail:pcheng@nankai.edu.cn
  • 基金项目:

    国家基金委创新团队(No.21421001) (No.21421001)

    教育部创新团队(IRT13022和13R30) (IRT13022和13R30)

    111引智计划(B12015) (B12015)

    天津市自然科学基金(13JCZDJC32200)资助项目。 (13JCZDJC32200)

摘要: 基于对已报道Gd-Cu配合物的文献调研,发现一类{LnCu3}簇合物(Ln=Gd(1), Tb(2), Dy(3)),其CuII离子被GdIII离子有效分隔且分子内部仅拥有铁磁相互作用,因而对其进行了低温磁制冷性能研究。在已报道实验方法上加以改进,用一锅法制备出一系列异金属{LnCu3}簇合物(Ln=Gd(1), Tb(2), Dy(3)),并运用元素分析、红外、单晶/粉末X-射线衍射等方法对其进行表征,以证明其同构性及相纯度。低温磁热效应的研究结果表明簇合物1-3在ΔH=0~7 T下的最大磁熵变值(-ΔSm)分别为16.1(2 K), 6.9(5 K)和8.1(5 K)J·kg-1·k-1。簇合物1与已报道的Gd-Cu簇合物的磁熵变对比再次证明了弱铁磁相互作用在3d-4f分子磁制冷剂设计中起到重要的作用。

English

  • 

    1. [1] Zheng Y Z, Zhou G J, Zheng Z, et al. Chem. Soc. Rev., 2014, 43(5):1462-1475[1] Zheng Y Z, Zhou G J, Zheng Z, et al. Chem. Soc. Rev., 2014, 43(5):1462-1475

    2. [2] Liu J L, Chen Y C, Guo F S, et al. Coord. Chem. Rev., 2014,281:26-49[2] Liu J L, Chen Y C, Guo F S, et al. Coord. Chem. Rev., 2014,281:26-49

    3. [3] SHI Peng-Fei (时鹏飞), XIONG Gang (熊刚), ZHANG Zhan-Yun (张战运), et al. Sci. China-Chem., 2013,43(10):1262-1271[3] SHI Peng-Fei (时鹏飞), XIONG Gang (熊刚), ZHANG Zhan-Yun (张战运), et al. Sci. China-Chem., 2013,43(10):1262-1271

    4. [4] Cremades E, Gómez-Coca S, Aravena D, et al. J. Am. Chem. Soc., 2012,134(25):10532-10542[4] Cremades E, Gómez-Coca S, Aravena D, et al. J. Am. Chem. Soc., 2012,134(25):10532-10542

    5. [5] Chang L X, Xiong G, Wang L, et al. Chem. Commun., 2013, 49(11):1055-1057[5] Chang L X, Xiong G, Wang L, et al. Chem. Commun., 2013, 49(11):1055-1057

    6. [6] Hou Y L, Xiong G, Shi P-F, et al. Chem. Commun., 2013,49(54):6066-6068[6] Hou Y L, Xiong G, Shi P-F, et al. Chem. Commun., 2013,49(54):6066-6068

    7. [7] Shi P F, Zheng Y Z, Zhao X Q, et al. Chem.-Eur. J., 2012,18(47):15086-15091[7] Shi P F, Zheng Y Z, Zhao X Q, et al. Chem.-Eur. J., 2012,18(47):15086-15091

    8. [8] Bing Y, Xu N, Shi W, et al. Chem.-Asian J., 2013,8(7):1412-1418[8] Bing Y, Xu N, Shi W, et al. Chem.-Asian J., 2013,8(7):1412-1418

    9. [9] Li H, Shi W, Niu Z, et al. Dalton Trans., 2015,44(2):468-471[9] Li H, Shi W, Niu Z, et al. Dalton Trans., 2015,44(2):468-471

    10. [10] Chen Y C, Qin L, Meng Z S, et al. J. Mater. Chem. A, 2014, 2(25):9851-9858[10] Chen Y C, Qin L, Meng Z S, et al. J. Mater. Chem. A, 2014, 2(25):9851-9858

    11. [11] Lorusso G, Sharples J W, Palacios E, et al. Adv. Mater., 2013,25(33):4653-4656[11] Lorusso G, Sharples J W, Palacios E, et al. Adv. Mater., 2013,25(33):4653-4656

    12. [12] Zhang S, Duan E, Cheng P. J. Mater. Chem. A, 2015,3(13):7157-7162[12] Zhang S, Duan E, Cheng P. J. Mater. Chem. A, 2015,3(13):7157-7162

    13. [13] Tishin A M, Spichkin Y I. The Magnetocaloric Effect and its Application. Bristol and Philadelphia:IOP Publishing, 2003.[13] Tishin A M, Spichkin Y I. The Magnetocaloric Effect and its Application. Bristol and Philadelphia:IOP Publishing, 2003.

    14. [14] Langley S K, Chilton N F, Moubaraki B, et al. Chem. Sci., 2011,2(6):1166-1169[14] Langley S K, Chilton N F, Moubaraki B, et al. Chem. Sci., 2011,2(6):1166-1169

    15. [15] Liu J L, Lin W Q, Chen Y C, et al. Inorg. Chem., 2013,52(1):457-463[15] Liu J L, Lin W Q, Chen Y C, et al. Inorg. Chem., 2013,52(1):457-463

    16. [16] Zhang H, Zhuang G L, Kong X J, et al. Cryst. Growth Des., 2013,13(6):2493-2498[16] Zhang H, Zhuang G L, Kong X J, et al. Cryst. Growth Des., 2013,13(6):2493-2498

    17. [17] Kettles F J, Milway V A, Tuna F, et al. Inorg. Chem., 2014,53(17):8970-8978[17] Kettles F J, Milway V A, Tuna F, et al. Inorg. Chem., 2014,53(17):8970-8978

    18. [18] Andruh M, Ramade I, Codjovi E, et al. J. Am. Chem. Soc., 1993,115(5):1822-1829[18] Andruh M, Ramade I, Codjovi E, et al. J. Am. Chem. Soc., 1993,115(5):1822-1829

    19. [19] Hooper T N, Schnack J, Piligkos S, et al. Angew. Chem. Int. Ed., 2012,51(19):4633-4636[19] Hooper T N, Schnack J, Piligkos S, et al. Angew. Chem. Int. Ed., 2012,51(19):4633-4636

    20. [20] Liu J L, Chen Y C, Li Q W, et al. Chem. Commun., 2013, 49(58):6549-6551[20] Liu J L, Chen Y C, Li Q W, et al. Chem. Commun., 2013, 49(58):6549-6551

    21. [21] Xiong G, Xu H, Cui J Z, et al. Dalton Trans., 2014,43(15):5639-5642[21] Xiong G, Xu H, Cui J Z, et al. Dalton Trans., 2014,43(15):5639-5642

    22. [22] Hooper T N, Inglis R, Palacios M A, et al. Chem. Commun., 2014,50(26):3498-3500[22] Hooper T N, Inglis R, Palacios M A, et al. Chem. Commun., 2014,50(26):3498-3500

    23. [23] Xue S, Guo Y N, Zhao L, et al. Inorg. Chem., 2014,53(15):8165-8171[23] Xue S, Guo Y N, Zhao L, et al. Inorg. Chem., 2014,53(15):8165-8171

    24. [24] Dermitzaki D, Lorusso G, Raptopoulou C P, et al. Inorg. Chem., 2013,52(18):10235-10237[24] Dermitzaki D, Lorusso G, Raptopoulou C P, et al. Inorg. Chem., 2013,52(18):10235-10237

    25. [25] Liu J L, Lin W Q, Chen Y C, et al. Chem.-Eur. J., 2013,19(51):17567-17577[25] Liu J L, Lin W Q, Chen Y C, et al. Chem.-Eur. J., 2013,19(51):17567-17577

    26. [26] Li Z Y, Wang Y X, Zhu J, et al. Cryst. Growth Des., 2013, 13(8):3429-3437[26] Li Z Y, Wang Y X, Zhu J, et al. Cryst. Growth Des., 2013, 13(8):3429-3437

    27. [27] Leng J D, Liu J L, Tong M L. Chem. Commun., 2012,48(43):5286-5288[27] Leng J D, Liu J L, Tong M L. Chem. Commun., 2012,48(43):5286-5288

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  • 收稿日期:  2015-06-01
  • 网络出版日期:  2015-07-14
通讯作者: 陈斌, bchen63@163.com
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