多孔有机骨架:基于傅氏烷基化反应的合成与气体吸附性质

引用本文: 崔鹏, 景晓飞, 任浩, 元野, 朱广山. 多孔有机骨架:基于傅氏烷基化反应的合成与气体吸附性质[J]. 无机化学学报, 2015, 31(9): 1855-1859. doi: 10.11862/CJIC.2015.256 shu

Citation: CUI Peng, JING Xiao-Fei, REN Hao, YUAN Ye, ZHU Guang-Shan. Porous Aromatic Frameworks: Synthesis via Friedel-Crafts Alkylation Reaction and Gas Sorption Property[J]. Chinese Journal of Inorganic Chemistry, 2015, 31(9): 1855-1859. doi: 10.11862/CJIC.2015.256 shu

多孔有机骨架:基于傅氏烷基化反应的合成与气体吸附性质

崔鹏 ^1, ,
景晓飞 ^2, ,
任浩 ^1, ,
元野 ^2, ,
朱广山 ^{1,
,}

1.
1. 吉林大学化学学院, 无机合成与制备化学国家重点实验室, 长春 130012;
2.
2. 东北师范大学化学学院, 多酸科学教育部重点实验室, 长春 130024

通讯作者: 朱广山,E-mail:zhugs@jlu.edu.cn

基金项目:
国家重点基础研究发展计划(973计划,No.2012CB821700,No.2014CB931804) (973计划,No.2012CB821700,No.2014CB931804)

国家自然科学基金委重大国际(地区)合作研究项目(No.21120102034)资助项目。 (地区)合作研究项目(No.21120102034)

摘要: 通过傅氏烷基化反应成功地合成了基于四苯锗烷构筑单元的多孔有机骨架材料PAF-9。用红外光谱,粉末X射线衍射,固体核磁共振,热重分析和低温氮气吸附-脱附表征了PAF-9材料的微结构与孔道性质。表征数据表明PAF-9具有非常高的热稳定性和化学稳定性,同时具有较高的比表面积。该PAF材料的BET比表面积为334 m²·g^-1。此外,得到的PAF材料对二氧化碳具有较好的吸附能力。

关键词:

傅氏烷基化;多孔有机骨架材料;气体吸附

English

Porous Aromatic Frameworks: Synthesis via Friedel-Crafts Alkylation Reaction and Gas Sorption Property

1.
1. State Key Laboratory of Inorganic Synthesis & Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China;
2.
2. Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Changchun 130024, China

Corresponding author: 朱广山,E-mail:zhugs@jlu.edu.cn

Received Date: 31 May 2015
Fund Project:
国家重点基础研究发展计划(973计划,No.2012CB821700,No.2014CB931804)

国家自然科学基金委重大国际(地区)合作研究项目(No.21120102034)资助项目。

Abstract: A porous aromatic framework, PAF-9 derived from tetraphenylgermane as basic building unit, was synthesized via Friedel-Crafts alkylation reaction. The microstructure and pore property were investigated by FTIR spectroscopy, powder X-ray diffraction, solid state NMR, thermogravimetric analysis and low temperature N₂ adsorption-desorption measurements. The characterizations reveal that PAF-9 possess high thermal and chemical stability as well as high BET surface area of 334 m²·g^-1. Additionally, the resulting PAF materials exhibit high CO₂ adsorption ability.

Key words:

Friedel-Crafts alkylation reaction;porous aromatic framework;gas sorption

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沈阳化工大学材料科学与工程学院沈阳 110142

多孔有机骨架:基于傅氏烷基化反应的合成与气体吸附性质

通讯作者: 朱广山,E-mail:zhugs@jlu.edu.cn

English

Porous Aromatic Frameworks: Synthesis via Friedel-Crafts Alkylation Reaction and Gas Sorption Property

Corresponding author: 朱广山,E-mail:zhugs@jlu.edu.cn

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

多孔有机骨架:基于傅氏烷基化反应的合成与气体吸附性质

通讯作者: 朱广山,E-mail:zhugs@jlu.edu.cn

English

Porous Aromatic Frameworks: Synthesis via Friedel-Crafts Alkylation Reaction and Gas Sorption Property

Corresponding author: 朱广山,E-mail:zhugs@jlu.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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