注册 English

一维和二维镝(Ⅲ)配合物的慢磁弛豫

吴建锋 ,  张海霞 ,  张鹏 ,  赵朗 ,  唐金魁

downloadPDF
引用本文: 吴建锋, 张海霞, 张鹏, 赵朗, 唐金魁. 一维和二维镝(Ⅲ)配合物的慢磁弛豫[J]. 无机化学学报, 2015, 31(9): 1847-1854. doi: 10.11862/CJIC.2015.236 shu
Citation:  WU Jian-Feng, ZHANG Hai-Xia, ZHANG Peng, ZHAO Lang, TANG Jin-Kui. Magnetic Relaxation in 1D and 2D Dysprosium(Ⅲ) Coordination Polymers[J]. Chinese Journal of Inorganic Chemistry, 2015, 31(9): 1847-1854. doi: 10.11862/CJIC.2015.236 shu

一维和二维镝(Ⅲ)配合物的慢磁弛豫

  • 1.

    中国科学院长春应用化学研究所, 稀土资源与利用国家重点实验室, 长春 130022

    • 通讯作者: 唐金魁,E-mail:tang@ciac.ac.cn
  • 基金项目:

    国家自然科学基金(No.21371166)资助项目。 (No.21371166)

摘要: 分别用稀土醋酸盐和稀土高氯酸盐与希弗碱配体和巯基烟酸配体反应得到了两例镝配合物[Dy2(OAc)6H2O]n(1)和{[DyL(H2O)4]ClO4·H2O}n(2)(L=2,2'-二硫代-二(3-吡啶甲酸)),并通过单晶X-射线衍射、元素分析、红外光谱和磁性测试对其进行了表征。结构研究和磁性测试表明:化合物1是羧基桥连的一维链结构,该化合物表现出慢磁弛豫性质,有效能垒为2 K;化合物2是通过原位生成的二硫键桥连的二维网状结构,表现出明显的铁磁相互作用和慢磁弛豫行为。

English

  • 

    1. [1] Zhang P, Guo Y N, Tang J. Coord. Chem. Rev., 2013,257:1728-1763[1] Zhang P, Guo Y N, Tang J. Coord. Chem. Rev., 2013,257:1728-1763

    2. [2] Gatteschi D, Sessoli R, Villain J. Molecular Nanomagnets. Oxford:Oxford University Press, 2006.[2] Gatteschi D, Sessoli R, Villain J. Molecular Nanomagnets. Oxford:Oxford University Press, 2006.

    3. [3] Zhang P, Zhang L, Tang J. Dalton Trans., 2015,44:3923-3929[3] Zhang P, Zhang L, Tang J. Dalton Trans., 2015,44:3923-3929

    4. [4] Stipe B C, Strand T C, Poon C C, et al. Nat. Photonics, 2010,4:484-488[4] Stipe B C, Strand T C, Poon C C, et al. Nat. Photonics, 2010,4:484-488

    5. [5] Zhang P, Tang J. Lanthanide Single Molecule Magnets. Heidelberg:Springer, 2015.[5] Zhang P, Tang J. Lanthanide Single Molecule Magnets. Heidelberg:Springer, 2015.

    6. [6] LIN Shuang-Yan(林双燕), GUO Yun-Nan(郭云南), TANG Jin-Kui(唐金魁), et al. Chinese J. Appl. Chem.(应用化学), 2010,27(12):1365-1371[6] LIN Shuang-Yan(林双燕), GUO Yun-Nan(郭云南), TANG Jin-Kui(唐金魁), et al. Chinese J. Appl. Chem.(应用化学), 2010,27(12):1365-1371

    7. [7] Blagg R J, Muryn C A, McInnes E J, et al. Angew. Chem. Int. Ed., 2011,50:6530-6533[7] Blagg R J, Muryn C A, McInnes E J, et al. Angew. Chem. Int. Ed., 2011,50:6530-6533

    8. [8] Blagg R J, Ungur L, Tuna F, et al. Nat. Chem., 2013,5:673-678[8] Blagg R J, Ungur L, Tuna F, et al. Nat. Chem., 2013,5:673-678

    9. [9] Liu J L, Wu J Y, Chen Y C, et al. Angew. Chem. Int. Ed., 2014,53:12966-12970[9] Liu J L, Wu J Y, Chen Y C, et al. Angew. Chem. Int. Ed., 2014,53:12966-12970

    10. [10] Lin S Y, Wernsdorfer W, Ungur L, et al. Angew. Chem. Int. Ed., 2012,51:12767-12771[10] Lin S Y, Wernsdorfer W, Ungur L, et al. Angew. Chem. Int. Ed., 2012,51:12767-12771

    11. [11] Tang J, Hewitt I, Madhu N T, et al. Angew. Chem. Int. Ed., 2006,45:1729-1733[11] Tang J, Hewitt I, Madhu N T, et al. Angew. Chem. Int. Ed., 2006,45:1729-1733

    12. [12] Guo Y N, Xu G F, Wernsdorfer W, et al. J. Am. Chem. Soc., 2011,133:11948-11951[12] Guo Y N, Xu G F, Wernsdorfer W, et al. J. Am. Chem. Soc., 2011,133:11948-11951

    13. [13] Zhang P, Zhang L, Wang C, et al. J. Am. Chem. Soc., 2014, 136:4484-4487[13] Zhang P, Zhang L, Wang C, et al. J. Am. Chem. Soc., 2014, 136:4484-4487

    14. [14] Guo Y N, Ungur L, Granroth G E, et al. Sci. Rep., 2014,4:5471[14] Guo Y N, Ungur L, Granroth G E, et al. Sci. Rep., 2014,4:5471

    15. [15] Rinehart J D, Fang M, Evans W J, et al. J. Am. Chem. Soc., 2011,133:14236-14239[15] Rinehart J D, Fang M, Evans W J, et al. J. Am. Chem. Soc., 2011,133:14236-14239

    16. [16] Joseph M Z, Dianne J X, Mihail Atanasov, et al. Nat. Chem., 2013,5:577-581[16] Joseph M Z, Dianne J X, Mihail Atanasov, et al. Nat. Chem., 2013,5:577-581

    17. [17] Rinehart J D, Fang M, Evans W J, et al. Nat. Chem., 2011,3:538-542[17] Rinehart J D, Fang M, Evans W J, et al. Nat. Chem., 2011,3:538-542

    18. [18] Ishikawa N, Sugita M, Ishikawa T, et al. J. Am. Chem. Soc., 2003,125:8694-8695[18] Ishikawa N, Sugita M, Ishikawa T, et al. J. Am. Chem. Soc., 2003,125:8694-8695

    19. [19] Ganivet C R, Ballesteros B, de la Torre G, et al. Chem. Eur. J., 2013,19:1457-1465[19] Ganivet C R, Ballesteros B, de la Torre G, et al. Chem. Eur. J., 2013,19:1457-1465

    20. [20] Woodruff D N, Winpenny R E P, Layfield R A. Chem. Rev., 2013,113:5110-5148[20] Woodruff D N, Winpenny R E P, Layfield R A. Chem. Rev., 2013,113:5110-5148

    21. [21] Dechambenoit P, Long J R. Chem. Soc. Rev., 2011,40:3249-3265[21] Dechambenoit P, Long J R. Chem. Soc. Rev., 2011,40:3249-3265

    22. [22] Bogani L, Sangregorio C, Sessoli R, Gatteschi D. Angew. Chem. Int. Ed., 2005,44:5817-5821[22] Bogani L, Sangregorio C, Sessoli R, Gatteschi D. Angew. Chem. Int. Ed., 2005,44:5817-5821

    23. [23] Jia L, Chen Q, Meng Y S, et al. Chem. Commun., 2014,50:6052-6055[23] Jia L, Chen Q, Meng Y S, et al. Chem. Commun., 2014,50:6052-6055

    24. [24] Pejo C, Guedes G P, Novak M A, et al. Chem. Eur. J., 2015,21:8696-8700[24] Pejo C, Guedes G P, Novak M A, et al. Chem. Eur. J., 2015,21:8696-8700

    25. [25] Shao D, Zhang S L, Zhao X H, et al. Chem. Commun., 2015, 51:4360-4363[25] Shao D, Zhang S L, Zhao X H, et al. Chem. Commun., 2015, 51:4360-4363

    26. [26] Caneschi A, Gatteschi D, Lalioti N, et al. Angew. Chem. Int. Ed., 2001,40:1760-1763[26] Caneschi A, Gatteschi D, Lalioti N, et al. Angew. Chem. Int. Ed., 2001,40:1760-1763

    27. [27] Norio I, Yoshitomo O, Susumu C, et al. J. Am. Chem. Soc., 2008,130:24-25[27] Norio I, Yoshitomo O, Susumu C, et al. J. Am. Chem. Soc., 2008,130:24-25

    28. [28] Feng X, Harris T D, Long J R. Chem. Sci., 2011,2:1688-1694[28] Feng X, Harris T D, Long J R. Chem. Sci., 2011,2:1688-1694

    29. [29] Zhang Y Z, Zhao H H, Funck E, et al. Angew. Chem. Int. Ed., 2015,54:5583-5587[29] Zhang Y Z, Zhao H H, Funck E, et al. Angew. Chem. Int. Ed., 2015,54:5583-5587

    30. [30] Sheldrick G M. SHELXS-97, Program for Crystal Structure Solution, University of Göttingen:Germany, 1997.[30] Sheldrick G M. SHELXS-97, Program for Crystal Structure Solution, University of Göttingen:Germany, 1997.

    31. [31] Boudreaux E A, Mulay L N. Theory and Applications of Molecular Paramagnetism. New York:John Wiley & Sons, 1976.[31] Boudreaux E A, Mulay L N. Theory and Applications of Molecular Paramagnetism. New York:John Wiley & Sons, 1976.

    32. [32] Kahn O. Molecular Magnetism. New York:VCH, 1993.[32] Kahn O. Molecular Magnetism. New York:VCH, 1993.

    33. [33] Xu G F, Wang Q L, Gamez P, et al. Chem. Commun., 2010, 46:1506-1508[33] Xu G F, Wang Q L, Gamez P, et al. Chem. Commun., 2010, 46:1506-1508

    34. [34] Leuenberger M N, Loss D. Nature, 2001,410:789-793[34] Leuenberger M N, Loss D. Nature, 2001,410:789-793

    35. [35] Plokhov D I, Popov A I, Zvezdin A K. Phys. Rev. B, 2011, 84:224436[35] Plokhov D I, Popov A I, Zvezdin A K. Phys. Rev. B, 2011, 84:224436

    36. [36] Wernsdorfer W, Sessoli R. Science, 1999,284:133-135[36] Wernsdorfer W, Sessoli R. Science, 1999,284:133-135

    37. [37] Bartolomé J, Filoti G, Kuncser V, et al. Phys. Rev. B, 2009, 80:014430[37] Bartolomé J, Filoti G, Kuncser V, et al. Phys. Rev. B, 2009, 80:014430

    38. [38] Lin S Y, Xu G F, Zhao L, et al. Dalton Trans., 2011,40:8213-8217[38] Lin S Y, Xu G F, Zhao L, et al. Dalton Trans., 2011,40:8213-8217

  • 加载中
WeChat 扫一扫看文章
计量
  • PDF下载量:  0
  • 文章访问数:  958
  • HTML全文浏览量:  139
文章相关
  • 收稿日期:  2015-05-29
  • 网络出版日期:  2015-07-13
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章

All Rights Reserved by the Chinese Chemical Society   中国化学会 版权所有 京ICP备05002797号

本系统由北京仁和汇智信息技术有限公司开发    技术支持: info@rhhz.net