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基于多齿希夫碱配体的四核和十核锰簇合物的合成、结构和磁性

杨晓迅 ,  冷际东 ,  刘俊良 ,  贾建华 ,  童明良

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引用本文: 杨晓迅, 冷际东, 刘俊良, 贾建华, 童明良. 基于多齿希夫碱配体的四核和十核锰簇合物的合成、结构和磁性[J]. 无机化学学报, 2015, 31(9): 1831-1838. doi: 10.11862/CJIC.2015.260 shu
Citation:  YANG Xiao-Xun, LENG Ji-Dong, LIU Jun-Liang, JIA Jian-Hua, TONG Ming-Liang. Synthesis, Structures and Magnetic Properties of Two Tetranuclear and Decanuclear Manganese Clusters Bearing the Multidentate Schiff-Base Ligands[J]. Chinese Journal of Inorganic Chemistry, 2015, 31(9): 1831-1838. doi: 10.11862/CJIC.2015.260 shu

基于多齿希夫碱配体的四核和十核锰簇合物的合成、结构和磁性

  • 1.

    中山大学化学与化学工程学院, 生物无机与合成化学教育部重点实验室, 广州 510275

    • 通讯作者: 贾建华,E-mail:jiajh3@mail.sysu.edu.cn
  • 基金项目:

    国家重点基础研究发展规划("973计划",No.2014CB845602,2012CB821704) ("973计划",No.2014CB845602,2012CB821704)

    国家自然科学基金(No.21301197,91122032,21371183,91422302) (No.21301197,91122032,21371183,91422302)

    广东省自然科学基金(S2013020013002) (S2013020013002)

    以及中央高校基本科研业务费专项资金(14lgpy10)资助项目。 (14lgpy10)

摘要: 合成了一种具有{NO4}给电子组成的多齿水杨醛希夫碱配体,3,5-二-叔丁基水杨醛-三(羟甲基)氨基甲烷(H4L),并利用元素分析、红外光谱以及核磁共振氢谱表征其结构。Mn(ClO4)2或MnCl2·4H2O分别与该配体在溶液中反应生成了一个四核锰簇合物[MnIII4(HL)2(H2L)2(MeCN)4](ClO4)2·2MeCN(1)和一个十核锰簇合物[MnIII6MnII4(bz)10(L)4(H2O)2]·10MeCN(2)。X-射线衍射分析表明化合物1的晶体结构空间群为三斜P1,而化合物2为正交Aba2。2~300 K温度区间的磁性测量数据表明化合物2中存在反铁磁相互作用。

English

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    1. [1] Sessoli R, Tsai H L, Schake A R, et al. J. Am. Chem. Soc., 1993,115:1804-1816[1] Sessoli R, Tsai H L, Schake A R, et al. J. Am. Chem. Soc., 1993,115:1804-1816

    2. [2] Sessoli R, Gatteschi D, Caneschi A, et al. Nature, 1993,365:141-143[2] Sessoli R, Gatteschi D, Caneschi A, et al. Nature, 1993,365:141-143

    3. [3] Aromí G, Brechin E K. Struct. Bond., 2006,122:1-67[3] Aromí G, Brechin E K. Struct. Bond., 2006,122:1-67

    4. [4] Friedman J R, Sarachik M P. Annu. Rev. Condens. Matter Phys., 2010,1:109-128[4] Friedman J R, Sarachik M P. Annu. Rev. Condens. Matter Phys., 2010,1:109-128

    5. [5] Gatteschi D, Sessoli R. Angew. Chem. Int. Ed., 2003,42:268-297[5] Gatteschi D, Sessoli R. Angew. Chem. Int. Ed., 2003,42:268-297

    6. [6] Christou G, Gatteschi D, Hendrickson D N, et al. MRS Bull., 2000,25:66-71[6] Christou G, Gatteschi D, Hendrickson D N, et al. MRS Bull., 2000,25:66-71

    7. [7] Ako A M, Hewitt I J, Mereacre V, et al. Angew. Chem. Int. Ed., 2006,45:4926-4929[7] Ako A M, Hewitt I J, Mereacre V, et al. Angew. Chem. Int. Ed., 2006,45:4926-4929

    8. [8] Manoli M, Prescimone A, Bagai R, et al. Inorg. Chem., 2007, 46:6968-6979[8] Manoli M, Prescimone A, Bagai R, et al. Inorg. Chem., 2007, 46:6968-6979

    9. [9] Moushi E E, Lampropoulos C, Wernsdorfer W, et al. Inorg. Chem., 2007,46:3795-3797[9] Moushi E E, Lampropoulos C, Wernsdorfer W, et al. Inorg. Chem., 2007,46:3795-3797

    10. [10] Murugesu M, Raftery J, Wernsdorfer W, et al. Inorg. Chem., 2004,43:4203-4209[10] Murugesu M, Raftery J, Wernsdorfer W, et al. Inorg. Chem., 2004,43:4203-4209

    11. [11] Rumberger E M, Shah S J, Beedle C C, et al. Inorg. Chem., 2005,44:2742-2752[11] Rumberger E M, Shah S J, Beedle C C, et al. Inorg. Chem., 2005,44:2742-2752

    12. [12] YAO Hong-Chang(要红昌), WANG Ning(王宁), LI Miao-Miao(李淼淼), et al. J. Zhengzhou Univ.:Nat. Sci. Ed. (郑州大学学报:理学版), 2008,40:88-94[12] YAO Hong-Chang(要红昌), WANG Ning(王宁), LI Miao-Miao(李淼淼), et al. J. Zhengzhou Univ.:Nat. Sci. Ed. (郑州大学学报:理学版), 2008,40:88-94

    13. [13] WANG Peng-Fei(汪鹏飞), WANG Xin(汪新), WU Guang-Hui(伍光辉), et al. Chinese J. Inorg. Chem. (无机化学学报), 2011,27:1881-1886[13] WANG Peng-Fei(汪鹏飞), WANG Xin(汪新), WU Guang-Hui(伍光辉), et al. Chinese J. Inorg. Chem. (无机化学学报), 2011,27:1881-1886

    14. [14] ZHOU Ai-Ju(周爱菊), LIANG Jing-Jing(梁晶晶), ZHENG Yan-Zhen(郑彦臻), et al. Chinese J. Inorg. Chem. (无机化学学报), 2012,28:2425-2430[14] ZHOU Ai-Ju(周爱菊), LIANG Jing-Jing(梁晶晶), ZHENG Yan-Zhen(郑彦臻), et al. Chinese J. Inorg. Chem. (无机化学学报), 2012,28:2425-2430

    15. [15] Fontecha J B, Goetz S, McKee V. Dalton Trans., 2005:923-929[15] Fontecha J B, Goetz S, McKee V. Dalton Trans., 2005:923-929

    16. [16] Oshio H, Hoshino N, Ito T, et al. J. Am. Chem. Soc., 2004, 126:8805-8812[16] Oshio H, Hoshino N, Ito T, et al. J. Am. Chem. Soc., 2004, 126:8805-8812

    17. [17] Oshio H, Hoshino N, Ito T, et al. Angew. Chem. Int. Ed., 2003,42:223-225[17] Oshio H, Hoshino N, Ito T, et al. Angew. Chem. Int. Ed., 2003,42:223-225

    18. [18] Oshio H, Nihei M, Yoshida A, et al. Chem. Eur. J., 2005, 11:843-848[18] Oshio H, Nihei M, Yoshida A, et al. Chem. Eur. J., 2005, 11:843-848

    19. [19] Oshio H, Nakano M. Chem. Eur. J., 2005,11:5178-5185[19] Oshio H, Nakano M. Chem. Eur. J., 2005,11:5178-5185

    20. [20] Bagai R, Abboud K A, Christou G. Dalton Trans., 2006:3306-3312[20] Bagai R, Abboud K A, Christou G. Dalton Trans., 2006:3306-3312

    21. [21] Hoshiko J A, Wang G, Ziller J W, et al. Dalton Trans., 2008:5712-5714[21] Hoshiko J A, Wang G, Ziller J W, et al. Dalton Trans., 2008:5712-5714

    22. [22] Sheldrick G M. SADABS, University of Göttingen, Germany, 2002.[22] Sheldrick G M. SADABS, University of Göttingen, Germany, 2002.

    23. [23] Sheldrick G M. Acta Crystallogr., 2008,A64:112-122[23] Sheldrick G M. Acta Crystallogr., 2008,A64:112-122

    24. [24] Hewitt I J, Tang J K, Madhu N T, et al. Chem. Commun., 2006:2650-2652[24] Hewitt I J, Tang J K, Madhu N T, et al. Chem. Commun., 2006:2650-2652

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  • 收稿日期:  2015-05-29
  • 网络出版日期:  2015-07-13
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