两个含[MS4Cu4]簇核的一维配位聚合物{[MS4Cu4(bpe)2(ani)2I2]·3.5ani}n(M=Mo,W;ani=苯胺)的组装及其晶体结构

刘泉 陈秋芳 虞虹 赵鑫 张文华 郎建平

引用本文: 刘泉, 陈秋芳, 虞虹, 赵鑫, 张文华, 郎建平. 两个含[MS4Cu4]簇核的一维配位聚合物{[MS4Cu4(bpe)2(ani)2I2]·3.5ani}n(M=Mo,W;ani=苯胺)的组装及其晶体结构[J]. 无机化学学报, 2015, 31(9): 1805-1810. doi: 10.11862/CJIC.2015.237 shu
Citation:  LIU Quan, CHEN Qiu-Fang, YU Hong, ZHAO Xin, ZHANG Wen-Hua, LANG Jian-Ping. Two One-Dimensional [MS4Cu4]-Supported Coordination Polymers: Assembly and Crystal Structures of {[MS4Cu4(bpe)2(ani)2I2]·3.5ani}n (M=Mo, W; ani=aniline)[J]. Chinese Journal of Inorganic Chemistry, 2015, 31(9): 1805-1810. doi: 10.11862/CJIC.2015.237 shu

两个含[MS4Cu4]簇核的一维配位聚合物{[MS4Cu4(bpe)2(ani)2I2]·3.5ani}n(M=Mo,W;ani=苯胺)的组装及其晶体结构

    通讯作者: 郎建平,E-mail:jplang@suda.edu.cn
  • 基金项目:

    国家自然科学基金(No.21373142,21371126)资助项目。 (No.21373142,21371126)

摘要: 前驱团簇[Et4N]4[MS4Cu4I6](M=Mo(1a);W(1b))与双齿桥连配体1,2-双(4-吡啶基)乙烷(bpe)在苯胺溶液中反应,生成2个结构相似的一维[MS4Cu4]团簇基配位聚合物{[MS4Cu4(bpe)2(ani)2I2]·3.5ani}n(M=Mo(2),W(3);ani=苯胺)。通过元素分析、红外光谱和X-射线单晶衍射对23进行了表征。晶体结构分析表明前驱团簇1a1b中五核马鞍形[MS4Cu4]簇核分别在23中得以保留,2个桥连配体bpe连接相邻的簇核,在[111]方向延伸形成一维"Z"字形链结构。

English

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  • 收稿日期:  2015-05-24
  • 网络出版日期:  2015-06-04
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