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准东次烟煤中长链烷醛的富集与分析

丛兴顺 ,  宗志敏 ,  周音 ,  李敏 ,  赵云鹏 ,  樊星 ,  魏贤勇

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引用本文: 丛兴顺, 宗志敏, 周音, 李敏, 赵云鹏, 樊星, 魏贤勇. 准东次烟煤中长链烷醛的富集与分析[J]. 燃料化学学报, 2014, 42(3): 257-261. shu
Citation:  CONG Xing-shun, ZONG Zhi-min, ZHOU Yin, LI Min, ZHAO Yun-peng, FAN Xing, WEI Xian-yong. Enrichment and analysis of long-chain normal alkanals from Zhundong subbituminous coal[J]. Journal of Fuel Chemistry and Technology, 2014, 42(3): 257-261. shu

准东次烟煤中长链烷醛的富集与分析

    通讯作者: ZONG Zhi-min,Tel:+86 51683995916,E-mail:zong_zhimin@163.com
  • 基金项目:

    National Basic Research Program of China (973 Program, 2011CB201302) (973 Program, 2011CB201302)

    the Key Project of Natural Science Foundation of China (20936007) (20936007)

    the Fund from Natural Science Foundation of China for Innovative Research Group (51221462) (51221462)

    the Key Project of Coal Joint Fund from Natural Science Foundation of China and Shenhua Group Corporation Limited (51134021) (51134021)

    The Strategic Chinese-Japanese Joint Research Program (2013DFG60060) (2013DFG60060)

    National Natural Science Foundation of China (51074153) (51074153)

    National Natural Science Foundation of China for Young Researchers (21206187 and 21206188) (21206187 and 21206188)

    the Priority Academic Program Development of Jiangsu Higher Education Institutions. 

摘要: 用等体积的二硫化碳(CDS)与丙酮的混合溶剂萃取了准东次烟煤得到可溶物,然后依次用石油醚(PE)和CDS萃取该可溶物为PE萃取物(E1)和CDS萃取物(E2)。在硅胶层析柱中依次用PE和30%的CDS/PE对E2进行洗脱,富集了长链烷醛(LCNAs,C18~27)并用气相色谱/质谱联用仪分析了LCNAs。分级萃取和柱层析提供了从中低阶煤中富集LCNAs的有效方法。LCNAs可能是煤中重要的生物标志物。

English

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  • 收稿日期:  2013-11-11
  • 网络出版日期:  2014-01-03
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