Two-dimensional correlation spectroscopic studies on coordination between carbonyl group of butanone and metalions

注册 English

Two-dimensional correlation spectroscopic studies on coordination between carbonyl group of butanone and metalions

Dan-Qing Gao , Xiao-Pei Li , Jia-Jia Shi , Xiao-Yan Kang , Ting-Guo Kang , Jin-Ming Xia , Xiao-Feng Ling , Shi-Fu Weng , Yi-Zhuang Xu , Isao Noda , Jin-Guang Wu

Citation: Dan-Qing Gao, Xiao-Pei Li, Jia-Jia Shi, Xiao-Yan Kang, Ting-Guo Kang, Jin-Ming Xia, Xiao-Feng Ling, Shi-Fu Weng, Yi-Zhuang Xu, Isao Noda, Jin-Guang Wu. Two-dimensional correlation spectroscopic studies on coordination between carbonyl group of butanone and metalions[J]. Chinese Chemical Letters, 2015, 26(2): 177-181. doi: 10.1016/j.cclet.2015.01.013 shu

shu

Two-dimensional correlation spectroscopic studies on coordination between carbonyl group of butanone and metalions

通讯作者: Ting-Guo Kang,
Yi-Zhuang Xu,

基金项目:
This project is financially supported by the National Natural Science Foundation of China (No. 51373003) (No. 51373003)

Beijing Natural Science Foundation (No. 2122059). (No. 2122059)

摘要: Two dimensional asynchronous spectra were used to characterize coordination between carbonyl group of butanone and metal ions by using an approach proposed in our recent paper. Spectral variation of n-π* transition band of carbonyl group is used to probe the coordination even if metal ions does not possess any characteristic peak in spectra. Experimental results indicate that Ca²⁺ and Al³⁺ show considerable ability to coordinate with the carbonyl group of butanone and bring about spectral variation of the n-π* transition band, which is manifested by cross peaks in 2D asynchronous spectra.

关键词:

English

Two-dimensional correlation spectroscopic studies on coordination between carbonyl group of butanone and metalions

1.
a School of Postgraduate, Liaoning University of Traditional Chinese Medicine, Shenyang 11660, China;
2.
b College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China;
3.
c Institute of Process Engineering and Chinese Academy of Sciences, Beijing 100190, China;
4.
d College of Chemistry and Materials, Hebei Normal University, Shijiazhuang 050016, China;
e Two Five Eight Health Technology Co.
e Two Five Eight Health Technology Co., Ltd, Beijing 100045, China;
6.
f The Third School of Clinical Medicine of Peking University, Beijing 100083, China;
g Ninghai Doubly Advanced Material Co.
g Ninghai Doubly Advanced Material Co., Ltd, Ninghai 315602, China;
8.
h Department of Materials Science and Engineering, University of Delaware, Newark, DE 19716, USA

Corresponding author: Ting-Guo Kang, Yi-Zhuang Xu,

Received Date: 30 October 2014
Available Online: 21 January 2015
Fund Project:

Abstract: Two dimensional asynchronous spectra were used to characterize coordination between carbonyl group of butanone and metal ions by using an approach proposed in our recent paper. Spectral variation of n-π* transition band of carbonyl group is used to probe the coordination even if metal ions does not possess any characteristic peak in spectra. Experimental results indicate that Ca²⁺ and Al³⁺ show considerable ability to coordinate with the carbonyl group of butanone and bring about spectral variation of the n-π* transition band, which is manifested by cross peaks in 2D asynchronous spectra.

Key words:

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