4’-羟基联苯-4-甲酸、1, 3-二吡啶基丙烷构筑的一维镉配位聚合物的晶体结构和荧光性质

引用本文: 马德运, 覃亮, 郭海福, 刘煌, 徐俊. 4’-羟基联苯-4-甲酸、1, 3-二吡啶基丙烷构筑的一维镉配位聚合物的晶体结构和荧光性质[J]. 无机化学学报, 2013, 29(11): 2503-2508. doi: 10.3969/j.issn.1001-4861.2013.00.354 shu

Citation: MA De-Yun, QIN Liang, GUO Hai-Fu, LIU Huang, XU Jun. One-Dimensional Cadmium Coordination Polymer Involving 4’-Hydroxybiphenyl-4-carboxylate and 1, 3-Bis(4-pyridyl)propane Ligands： Structure and Luminescence[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(11): 2503-2508. doi: 10.3969/j.issn.1001-4861.2013.00.354 shu

4’-羟基联苯-4-甲酸、1, 3-二吡啶基丙烷构筑的一维镉配位聚合物的晶体结构和荧光性质

马德运 ^1, ,
覃亮 ^1, ,
郭海福 ^1, ,
刘煌 ^1, ,
徐俊 ^2,

基金项目:
广东省教育厅育苗工程(2012LYM_0134) (2012LYM_0134)

国家自然科学基金(No.81202461) (No.81202461)

中国博士后基金(2013M531906)资助项目 (2013M531906)

摘要: 水热条件下采用Cd(NO₃)₂·4(H₂O),4'-羟基联苯-4-甲酸和1,3-二吡啶基丙烷作为反应物合成出一个新的一维镉配位聚合物{[Cd(4',4-Hhbc)₂(bpp)₂]}_n(1)(4',4-H₂hbc=4'-羟基联苯-4-甲酸,bpp=1,3-二吡啶基丙烷),并分别用元素分析、红外光谱、差热分析、X-射线粉末衍射、紫外吸收光谱和X-射线单晶衍射等表征了该结构。晶体结构分析结果表明:μ₂桥联的1,3-二吡啶基丙烷将镉金属离子连接成一维链结构。荧光分析表明常温固态下配合物1发射蓝色荧光,且在440nm处的荧光寿命为3.2ns。

关键词:

镉配位聚合物;水热合成;晶体结构;荧光性质

English

One-Dimensional Cadmium Coordination Polymer Involving 4’-Hydroxybiphenyl-4-carboxylate and 1, 3-Bis(4-pyridyl)propane Ligands： Structure and Luminescence

1.
1 School of Chemistry and Chemical Engineering, Zhaoqing University, Zhaoqing, Guangdong 526061, China;
Received Date: 13 April 2013
Fund Project:
广东省教育厅育苗工程(2012LYM_0134)

国家自然科学基金(No.81202461)

中国博士后基金(2013M531906)资助项目

Abstract: A new 1Dcadmium(Ⅱ) coordination polymer, {[Cd(4',4-Hhbc)₂(bpp)₂]}_n (1, 4',4-Hhbc=4'-Hydroxyl-biphenyl-4-carboxylate, bpp=1,3-bis(4-pyridyl)propane), has been hydrothermally synthesized and structurally characterized by elemental analysis, IRspectroscopy, TGA, powder X-ray diffraction, UV-Vis and single crystal X-ray diffraction. Structural determination reveals that 1 exhibits an interesting 1D chain structure. Solid-state 1 emits the intensely indigotin photoluminescence with fluorescence lifetime of 3.2 ns (440 nm) at room temperature. CCDC: 854723.

Key words:

cadmium(Ⅱ) coordination polymer;hydrothermal synthesis;crystal structure;luminescence

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沈阳化工大学材料科学与工程学院沈阳 110142

4’-羟基联苯-4-甲酸、1, 3-二吡啶基丙烷构筑的一维镉配位聚合物的晶体结构和荧光性质

English

One-Dimensional Cadmium Coordination Polymer Involving 4’-Hydroxybiphenyl-4-carboxylate and 1, 3-Bis(4-pyridyl)propane Ligands： Structure and Luminescence

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

4’-羟基联苯-4-甲酸、1, 3-二吡啶基丙烷构筑的一维镉配位聚合物的晶体结构和荧光性质

English

One-Dimensional Cadmium Coordination Polymer Involving 4’-Hydroxybiphenyl-4-carboxylate and 1, 3-Bis(4-pyridyl)propane Ligands： Structure and Luminescence

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

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