一种2, 2’-联咪唑镉化合物的荧光、理论计算和结构研究

陈文通

引用本文: 陈文通. 一种2, 2’-联咪唑镉化合物的荧光、理论计算和结构研究[J]. 无机化学学报, 2013, 29(11): 2455-2459. doi: 10.3969/j.issn.1001-4861.2013.00.364 shu
Citation:  CHEN Wen-Tong. Fluorescent, Theoretical and Structural Investigations of a 2, 2’-Biimidazole Cadmium Compound[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(11): 2455-2459. doi: 10.3969/j.issn.1001-4861.2013.00.364 shu

一种2, 2’-联咪唑镉化合物的荧光、理论计算和结构研究

  • 基金项目:

    科技部科技支撑计划(No.2012BAC11B01)资助项目 (No.2012BAC11B01)

摘要: 通过水热反应合成了一种新颖的镉-联咪唑化合物[Cd(BIm)2](ClO4)(OH)·2H2O(1)(BIm=2,2'-biimidazole),并对其进行了单晶X-射线衍射结构表征。该化合物具有孤立结构特征,镉原子与4个氮原子配位形成1个扭曲的四面体。光致发光研究发现该化合物发出蓝色荧光。理论研究结果显示该荧光来自于LMCT机理。本文还对其红外光谱进行了报道。

English

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  • 收稿日期:  2012-11-29
  • 网络出版日期:  2013-04-28
通讯作者: 陈斌, bchen63@163.com
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