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两个含吡啶取代苯酚配体的铜配合物的合成与晶体结构

高大志 ,  王若徐 ,  叶帆 ,  沈旋 ,  许岩 ,  朱敦如

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引用本文: 高大志, 王若徐, 叶帆, 沈旋, 许岩, 朱敦如. 两个含吡啶取代苯酚配体的铜配合物的合成与晶体结构[J]. 无机化学学报, 2013, 29(11): 2438-2444. doi: 10.3969/j.issn.1001-4861.2013.00.384 shu
Citation:  GAO Da-Zhi, WANG Ruo-Xu, YE Fan, SHEN Xuan, XU Yan, ZHU Dun-Ru. Syntheses and Crystal Structures of Two Copper Complexes with Pyridyl-Substituted Phenol Ligand[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(11): 2438-2444. doi: 10.3969/j.issn.1001-4861.2013.00.384 shu

两个含吡啶取代苯酚配体的铜配合物的合成与晶体结构

  • 基金项目:

    国家自然科学基金(No.21171093) (No.21171093)

    南京工业大学材料化学工程国家重点实验室开放课题(KL11-03)资助项目。 (KL11-03)

摘要: 以2-[N,N-二(2-吡啶甲基)氨甲基]-6-醛基-4-甲基苯酚(L)为配体,合成了2个单核铜配合物[CuL(CH3CN)(ClO4)]ClO4(1)和cis-[CuL(NCS)2]·0.5C4H8O2(2),对它们进行了紫外、红外、质谱、元素分析和单晶结构表征。2个配合物都属于单斜晶系,每个铜均为扭曲的八面体构型。作为四齿配体,L通过2个吡啶氮原子,1个叔胺氮原子和1个酚氧原子和铜离子配位。在配合物1中,乙腈和1个ClO4-参与配位,而在配合物2中2个硫氰根离子为顺式配位。

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  • 收稿日期:  2013-05-17
  • 网络出版日期:  2013-06-09
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