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基于三聚硫氰酸配体的六核镍配合物的合成, 晶体结构和荧光性能分析

陈静 ,  谢吉民 ,  夏昌坤 ,  朱禹 ,  陈佳

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引用本文: 陈静, 谢吉民, 夏昌坤, 朱禹, 陈佳. 基于三聚硫氰酸配体的六核镍配合物的合成, 晶体结构和荧光性能分析[J]. 无机化学学报, 2013, 29(11): 2433-2437. doi: 10.3969/j.issn.1001-4861.2013.00.339 shu
Citation:  CHEN Jing, XIE Ji-Min, XIA Chang-Kun, ZHU Yu, CHEN Jia. Synthesis, Characterization and Photoluminescent Property of a Hexanuclear Nickel(Ⅱ) Complex with Trithiocyanuric Acid[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(11): 2433-2437. doi: 10.3969/j.issn.1001-4861.2013.00.339 shu

基于三聚硫氰酸配体的六核镍配合物的合成, 晶体结构和荧光性能分析

  • 基金项目:

    国家自然科学基金(No.21171075/B010303) (No.21171075/B010303)

    教育部博士点基金(No.20093227110009) (No.20093227110009)

    江苏省自然科学基金(No.BK2010166)资助项目。 (No.BK2010166)

摘要: 用缓慢挥发法合成了一个六核Ni(Ⅱ)的配位聚合物[Ni6(H2O)6(HTMT)6]·3(C2H5)3N·7H2O(1)(H3TMT=三聚硫氰酸),并用红外、元素分析及单晶衍射进行表征。该配合物属于三方晶系,R3c空间群,晶胞参数为a=b=1.8697(3)nm,c=3.9825(8)nm,γ=120°。晶胞体积V=12.057(4)nm3,Dc=1.596gcm-3,Z=6,μ=1.91mm-1,F(000)=6095,R=0.047,wR=0.151。X单晶衍射表明,6个Ni(Ⅱ)与6个HTMT2-和6个水分子形成一个六核的构筑单元,这个六核构筑单元又通过氢键作用形成三维结构。同时在室温条件下测定了该配合物的荧光性能。

English

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  • 收稿日期:  2013-02-16
  • 网络出版日期:  2013-03-18
通讯作者: 陈斌, bchen63@163.com
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